初始化

Out of the Cradle Endlessly Rocking Pub Date : 2005-01-01 DOI:10.1163/9789004488380_004

{"title":"初始化","authors":"","doi":"10.1163/9789004488380_004","DOIUrl":null,"url":null,"abstract":"1. explain why the radical halogenation of alkanes is not usually a particularly good method of preparing pure samples of alkyl halides. 2. use \\(\\ce{\\sf{C–H}}\\) bond energies to account for the fact that in radical chlorinations, the reactivity of hydrogen atoms decreases in the order \\[\\text{tertiary} > \\text{secondary} > \\text{primary}.\\] 3. predict the approximate ratio of the expected products from the monochlorination of a given alkane.","PeriodicalId":129263,"journal":{"name":"Out of the Cradle Endlessly Rocking","volume":"12 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2005-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Initiation\",\"authors\":\"\",\"doi\":\"10.1163/9789004488380_004\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"1. explain why the radical halogenation of alkanes is not usually a particularly good method of preparing pure samples of alkyl halides. 2. use \\\\(\\\\ce{\\\\sf{C–H}}\\\\) bond energies to account for the fact that in radical chlorinations, the reactivity of hydrogen atoms decreases in the order \\\\[\\\\text{tertiary} > \\\\text{secondary} > \\\\text{primary}.\\\\] 3. predict the approximate ratio of the expected products from the monochlorination of a given alkane.\",\"PeriodicalId\":129263,\"journal\":{\"name\":\"Out of the Cradle Endlessly Rocking\",\"volume\":\"12 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2005-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Out of the Cradle Endlessly Rocking\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1163/9789004488380_004\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Out of the Cradle Endlessly Rocking","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1163/9789004488380_004","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

1. 解释为什么烷烃的自由基卤化通常不是制备纯烷基卤化物样品的特别好的方法。2. 用\(\ce{\sf{C–H}}\)键能来解释在自由基氯化反应中，氢原子的反应活性按\[\text{tertiary} > \text{secondary} > \text{primary}.\] 3的顺序递减的事实。预测给定烷烃单氯化反应中预期产物的大致比例。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Initiation

1. explain why the radical halogenation of alkanes is not usually a particularly good method of preparing pure samples of alkyl halides. 2. use \(\ce{\sf{C–H}}\) bond energies to account for the fact that in radical chlorinations, the reactivity of hydrogen atoms decreases in the order \[\text{tertiary} > \text{secondary} > \text{primary}.\] 3. predict the approximate ratio of the expected products from the monochlorination of a given alkane.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Out of the Cradle Endlessly Rocking

自引率

0.00%

发文量