采用LC-MS/MS和GC-MS/MS耦合QuEChERS方法测定智利农业生物量(Capsicum annuum L.)中的农药残留

e-CUCBA Pub Date : 2023-06-29 DOI:10.32870/ecucba.vi20.301
L. A. JIMÉNEZ-ORTEGA, P. D. J. Bastidas-Bastidas, Octavio Valdez-Baro, Manuel Alonzo Báez-Sañudo, J. Basilio Heredia
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引用次数: 0

摘要

园艺作物的集约化生产产生了大量的农业生物质(BA),这些生物质被露天焚烧或堆积在垃圾填埋场,成为一个环境问题,特别是当它们被农药残留污染时。采用LC/MS-MS和GC/MS/MS联用技术,对甜椒、jalapeño辣椒和黑胡椒的BA中农药残留量进行了测定。对世界各国的规定进行了比较,对最大残留限量进行了分析。对3种BA的农药残留进行了定量分析,其中jalapeño和辣椒的污染最严重,重点是蓝氯氰菊酯(1.11 mg/kg⁻¹)、联苯菊酯(1.62 mg/kg⁻¹)、氯氰菊酯(0.34mg/kg⁻¹)、吡虫啉(4.51 mg/kg⁻¹)和氯氰嗪(4.04 mg/kg⁻¹)。在广管局中发现了农药残留,因此建议对其处置进行监管和监测。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Residuos de plaguicidas en biomasa agrícola de chile (Capsicum annuum L.) usando un método QuEChERS acoplado a LC-MS/MS y GC-MS/MS
The intensive production of horticultural crops generates large amounts of agricultural biomass (BA), which is burned in the openfield or deposited in landfills becoming an environmental problem, especially if they are contaminated by pesticide residues. Thestudy aimed to evaluate the presence of pesticides in the BA of bell pepper, jalapeño pepper, and poblano pepper, using aQuEChERS method coupled to LC/MS-MS and GC/MS/MS. An analysis of the maximum residue limits was carried out,contrasting different regulations worldwide. Pesticide residues were quantified in the three BA, with jalapeño and poblano peppersbeing the most contaminated, highlighting lambda-cyhalothrin (1.11 mg/kg⁻¹), bifenthrin (1.62 mg/kg⁻¹), cypermethrin (0.34mg/kg⁻¹), imidacloprid (4.51 mg/kg⁻¹) and cyromazine (4.04 mg/kg⁻¹). Pesticide residues were identified in the BA, so its disposalis recommended to be regulated and monitored.
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