D. Toshpulatov, Sh.E. Mirzaev, A. Nasimov, B. A. Yakubov, A. A. Samiev, Kh. Sh. Tashpulatov
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引用次数: 0
摘要
合成了[Co(py)(SCN) 4 ] 2+ 复合物，并在有机溶剂和基于四乙氧基硅烷的溶胶-凝胶膜中对其光化学性质进行了研究。基于 TEOS 的溶胶-凝胶膜显示出合适的基质，钴染料在膜孔内保留了其光化学性质。根据溶胶凝胶膜基质的光谱变化，还讨论了分子形状的可能变化。此外，溶胶-凝胶膜还证实了钴复合物不会发生光漂白或降解。
SYNTHESIS OF [CO(BPY)(SCN)4]2+ COMPLEX AND ITS PHOTOCHEMICAL PROPERTIES IN THE SOL-GEL MATRIX
. Synthesis of [Co(bpy)(SCN) 4 ] 2+ complex carried and its photochemical properties studies explored in both organic solvent and tetraethoxysilane based sol-gel membrane. TEOS based sol-gel membrane shown suitable matrix and cobalt dye retain its photochemical properties inside the pores of membrane. Based on spectral changes in the sol-gel ma matrix, possible changes in molecular shape also discussed. Moreover, the sol-gel membrane confirm cobalt complex from photobleaching or degradation.
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