化学氧化法制备InP太阳能电池的有效第一层抗反射涂层

M. Faur, M. Faur, D. Flood, D. Brinker, C. Goradia, S. Bailey, I. Weinberg, M. Goradia, D. Jayne, J. Moulot, N. Fatemi
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引用次数: 5

摘要

通常用于InP太阳能电池的第一层增透(AR)涂层,如ZnS、Sb/sub 2/O/sub 3/、SiO/sub 2/和SiO,通过电子束或电阻蒸发沉积,破坏了发射极表面的化学计量。因此,发射极表面的表面复合速度(SRV)显著增加,导致太阳能电池性能参数值降低。这可以通过在接触后在发射极表面生长薄的天然氧化层来防止。采用基于HNO/sub 3/、O -H/sub 3/PO/sub 4/和H/sub 2/O/sub 2/的新型蚀刻剂(PNP)进行化学氧化,获得了最佳的富磷化学氧化物。化学氧化物生长在p/sup +/-InP发射器上,使用PNP腐蚀剂,使表面钝化,可用作第一层AR涂层。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effective first layer antireflective coating on InP solar cells grown by chemical oxidation
Commonly used first layer antireflection (AR) coatings for InP solar cells, such as ZnS, Sb/sub 2/O/sub 3/, SiO/sub 2/ and SiO, deposited either by electron-beam or by resistive evaporation, destroy the stoichiometry of the emitter surface. Consequently, the surface recombination velocity (SRV) at the emitter surface is significantly increased, leading to a reduction in the values of solar cell performance parameters. This can be prevented by growing, after contacting, a thin native oxide layer on the emitter surface. Best results are obtained using a phosphorus-rich chemical oxide grown by chemical oxidation using a newly developed etchant (PNP) based on HNO/sub 3/, o-H/sub 3/PO/sub 4/ and H/sub 2/O/sub 2/. The chemical oxide grown on p/sup +/-InP emitters, using the PNP etchant, passivates the surface and can be used as a first layer AR coating.<>
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