用活性炭去除油菜籽废水中的Pb2+和Cd2+

A. C. G. Júnior, A. Schiller, Elio Conradi Junior, Jéssica Manfrin, D. Schwantes, Juliano Zimmermann, Gabriel José Klassen, Marcelo Ângelo Campagnolo
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引用次数: 2

摘要

本研究的目的是利用油菜籽废弃物化学制备活性炭,并将所制备的活性炭应用于污染水体中铅和镉的吸附。用NaOH (1 mol L)连续搅拌6 h活化油菜籽废弃物。然后将活性物质在750℃下热解1h。采用硝基高氯酸消化法测定活性炭中的P、K、Ca、Mg、Mn、Zn、Cu和Pb。并对其进行了热重评价(TG)、红外光谱分析(FT-IR)、pHPCZ和扫描电镜(SEM)等。对金属进行了吸附剂剂量、pH、动力学、热力学和平衡参数的理想评价。质量和pH值结果表明,4克吸附剂需要净化1升污染溶液。采用Langmuir、Freundlich和D-R数学模型进行线性化处理,对两种金属均有较高的去除能力。因此,利用油菜籽废料生产活性炭不仅可以增加油菜籽废料的价值,而且可以直接促进这一生产系统的经济、社会和环境可持续性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Removal of Pb2+ and Cd2+ From Contaminated Water Using Activated Carbon from Canola Seed Wastes
The objective of this work was to produce activated carbon chemically from canola seeds wastes and to apply the activated carbon produced in the sorption of Pb and Cd from contaminated water. The activation of the canola seeds wastes was performed with NaOH (1 mol L) for 6 h under constant stirring. Then the activated material was pyrolyzed for 1 h at 750 °C. The activated carbon was subjected to nitroperchloric digestion for the determination of P, K, Ca, Mg, Mn, Zn, Cu and Pb by flame atomic absorption spectrometry (FAAS). It was also realized the thermogravimetric evaluation (TG), infrared spectra (FT-IR), pHPCZ and scanning electron microscopy (SEM). The metals were evaluated for ideal amounts of adsorbent dose and pH and kinetic, thermodynamic and equilibrium parameters. The mass and pH results demonstrated that four grams of adsorbent is needed to decontaminate one liter of contaminated solution. Linearization were obtained by the mathematical models of Langmuir, Freundlich and D-R, with high capacity of removal of both metals. Thus, using canola waste to produce activated carbon it is possible to add value to the canola seed wastes, also, it contributes directly with the economic, social and environmental sustainability of this productive system.
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