阵列柔性染料敏化太阳能电池中相互电解质结构的分析

Shen-Wei Chuang, J. Chou, Yi-Hung Liao, Jui-En Hu, Shu-huei Huang, Shen-Chang Lin, Hsueh-Tao Chou
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引用次数: 0

摘要

在本研究中,采用阵列柔性染料敏化太阳能电池(FDSSC)的互电解质结构来降低内部阻抗。采用蚀刻液在ITO- pet衬底上蚀刻导电层(ITO),设计出阵列图案。采用自旋镀膜的方法在导电衬底上制备了TiO2薄膜。具有互电解质结构的阵列柔性染料敏化太阳能电池可以很好地避免电解质直接接触ITO层,提高光伏转换效率。具有互电解质结构的阵列柔性染料敏化太阳能电池具有多余的电解质,可以从互电解质结构的电池与电池之间的缝隙中获得足够的氧化还原。比较了不同距离电池与电池之间的相互电解质结构,并通过光伏特性参数和电化学阻抗谱(EIS)对实验结果进行了验证。实验结果表明,在1 mm距离处,开路电压(VOC)为0.81 V,短路电流密度(JSC)为1.70 mA/cm2,光伏转换效率为0.37%时,具有最优特性参数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Analysis of mutual electrolyte structure applied in arrayed flexible dye-sensitized solar cells
In this study, the mutual electrolyte structure of arrayed flexible dye-sensitized solar cell (FDSSC) was used to decrease the internal impedance. The ITO-PET substrate was etched the conductive layer (ITO) by etching solution, which designed arrayed pattern. TiO2 thin film was fabricated on the arrayed conductive substrate by spin-coating. The arrayed flexible dye-sensitized solar cell with mutual electrolyte structure can be well avoided electrolyte to contact ITO layer directly, which increased photovoltaic conversion efficiency. The arrayed flexible dye-sensitized solar cell with mutual electrolyte structure has excess electrolyte, which can obtain sufficient redox from crevice between cell and cell of mutual electrolyte structure. Compared different distances between cell and cell of mutual electrolyte structure, and the experimental results were confirmed by photovoltaic characteristic parameters and Electrochemical Impedance Spectroscopy (EIS). According to the experimental results, the distance of 1 mm has optimal characteristic parameter, which the open circuit voltage (VOC) is 0.81 V, the short circuit current density (JSC) is 1.70 mA/cm2, and the photovoltaic conversion efficiency is 0.37 %.
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