交换相关自旋线性链中的佩尔跃迁

N. Orlova, M. Kurkin
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引用次数: 0

摘要

在一个新的磁亚晶格模型的框架下,计算了物质的反铁磁态相对于佩尔斯跃迁的稳定性损失。在这个新模型中,与Anderson-Ziman亚晶格模型相比,反铁磁自旋有序是由磁各向异性的微弱影响提供的。磁各向异性抑制交换混合与足够多的自旋在亚晶格中。佩尔斯跃迁存在于原子线性链的变形中,即相邻原子的收敛,此时晶格的周期增加了两倍。当原子靠近时,交换作用仅在最近的一对原子自旋之间建立。基于新的磁亚晶格模型,发现自旋周期链的反铁磁亚晶格态相对于向佩尔斯态的过渡是不稳定的。在向“自旋-佩尔斯”状态过渡的过程中,相邻原子的自旋将是反平行有序的,但由于没有自旋有序的首选方向,因此不可能引入磁亚晶格的概念。这种磁态可以从磁化率与倒数温度的指数关系中得到。如果热运动频率比交换频率小,则该状态下的电子磁性由原子抗磁性决定。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Peierles transition in a linear chain of exchange related spins
The loss of stability of the antiferromagnetic state of matter respective to the Peierls transition is calculated in the framework of a new model of magnetic sublattices. In this new model, in contrast to the Anderson-Ziman sublattice model, the antiferromagnetic spin ordering is provided by a weak influence of magnetic anisotropy. Magnetic anisotropy suppresses exchange mixing with a sufficiently large number of spins in the sublattice . The Peierls transition consists in the deformation in a linear chain of atoms, namely the convergence of neighboring atoms, at which the period of the crystal lattice increases by factor of two. When atoms approach, exchange interaction is established between a pair of nearest atomic spins only. Based on the new model of magnetic sublattices, the antiferromagnetic sublattice state of the periodic chain of spins is found to be unstable respective to the transition to the Peierls state. During the transition to the "spin-Peierls" state, the spins of neighboring atoms will be ordered antiparallelly, but since there is no preferred direction of spin ordering, it is impossible to introduce the concept of magnetic sublattices. Such magnetic states can be suggested from the exponential dependence of the magnetic susceptibility on the reciprocal temperature. The electrons magnetism in this state is determined by the atomic diamagnetism if the frequencies of thermal motion are small compared to the exchange frequency.
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