用于液化石油气(LPG)传感器的丙烯酸基聚苯胺复合材料

M. Panigrahi, B. Adhikari
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引用次数: 0

摘要

n -苯基-β-丙氨酸(n -取代苯胺)得到n -取代聚苯胺。以丙烯酸甲酯和苯胺为原料,化学合成了n -苯基β-丙氨酸。采用ESI-MS、H1NMR和FTIR对n -苯基β-丙氨酸进行了表征,并对其结构进行了分析。通过x射线衍射、FTIR、uv -可见、H1NMR、FESEM、溶解度和直流电导率等手段研究了聚合物的结构和性能。在实验结果的基础上,提出了n -取代苯胺单体及其相应的聚合物。室温下制备的聚苯胺聚合物的平均直流电导率在半导体范围内,聚3-甲基苯基氨基丙酸的平均直流电导率为0.153 S/cm。我们还分析了制备的聚苯胺聚合物在有磁场和没有磁场的情况下随温度变化的直流电导率,以了解导电机理,并遵循变范围跳变(VRH)过程。此外,我们还讨论了聚苯胺基传感器材料对液化石油气(LPG)的响应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Acrylic Acid (AA) Based Polyaniline Composite for Liquified Petroleum Gas (LPG) Sensors
N-substituted PANI-ES was obtained from N-phenyl-β-alanine (N-substituted aniline). N-phenyl-β-alanine was synthesized chemically from methyl acrylate and aniline precursor. ESI-MS, H1NMR spectroscopy and FTIR spectroscopy are employed to characterise the N-phenyl-β-alanine for structure elucidation. The structure and properties of corresponding polymers were investigated by X-ray diffraction, FTIR, UV-Visible, H1NMR, FESEM, solubility, and DC conductivity. On the basis of experimental results of prepared N-substituted aniline monomer and its corresponding polymer is proposed. At room temperature, the average DC conductivity of as-prepared PANI polymers was found in semiconducting range, which is 0.153 S/cm for poly (3-methyl (phenyl amino) propionic acid. We also were analysed temperature dependent DC conductivity with and without magnetic field of as prepared PANI polymers to understand the conduction mechanism and it was followed variable-range hopping (VRH) process. In addition, we were discussed the response of liquefied petroleum gas (LPG) with polyaniline based sensor materials.
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