一种新的斑点地衣的分离和结构分析

Olivio Nino Castro, Jesus Miguel López Rodilla, S. Pombal, Francisca Sanz González, Julio Santiago Contreras
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引用次数: 0

摘要

在本研究中,分离到了一种新的疣状地衣。干燥样品400 g,乙醇研磨3次,CHCl3-MeOH体系柱层析分离,meoh -丙酮(1:1)重结晶纯化;最后得到针状白色晶体(固体C),熔点198℃,通过光谱数据(UV-Visible, IR, NMR-H1, NMR-C13,质谱和单晶x射线衍射)对其结构进行了分析。根据Science Finder的数据库,这是一种新的深度,称为trullarin,并且观察到分子包装受到分子内和分子间力的影响。O - H -O型分子间氢键结合相邻分子形成二聚体。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ISOLATION AND STRUCTURAL ELUCIDATION OF A NEW DEPSIDE OF LICHEN Everniopsis trulla
In this research, a new depside of the lichen Everniopsis trulla has been isolated. The extraction was carried out to 400 g of dry sample and ground with ethanol for 3 repetitions, then, it was fractionated by applying column chromatography with the CHCl3-MeOH system and purified by recrystallization with MeOH-Acetone (1: 1); Finally, white crystals in the form of needles (solid C) with a melting point of 198 ° C were obtained, whose structure was elucidated based on spectroscopic data (UV-Visible, IR, NMR-H1, NMR-C13, mass spectrometry and single crystal X-ray diffraction). According to the Science Finder databases, it is a new depside, called trullarin, and it is observed that molecular packing is influenced by both intramolecular and intermolecular forces. Intermolecular hydrogen bonds of O - H -O type binds neighboring molecules forming dimers.
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