提高钙钛矿- cdte串联太阳能电池的效率和稳定性:wx-AMPS的数值模拟研究

Sharmin Jahan, Rudaina Tasnuva, M. A. Matin
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引用次数: 1

摘要

有机和无机卤化铅钙钛矿由于其重量轻、效率高、成本低等特点,在过去十年中在光伏技术中发挥了重要作用。作为吸收层,甲基溴化铅基钙钛矿电池具有2.3 eV的带隙,这使得它们与能量间隙为1.45 eV的CdTe太阳能电池兼容串联结构。本研究利用wx-AMPS模拟技术建立了钙钛矿- cdte串联太阳能电池的低成本器件配置模型。单结钙钛矿太阳能电池的效率为21.8%,单结CdTe太阳能电池的效率为25.71%。吸收层(钙钛矿和CdTe)的厚度和掺杂物浓度、空穴输运材料(HTM)、电子输运材料(ETM)以及器件温度都对太阳能电池的输出参数和性能有影响。CdTe和钙钛矿的理想厚度分别为4µm和6µm,效率最高。在开路电压为0.9997 V,短路电流为33.91 mA/cm2,填充系数为87%的条件下,FTO(TCO)/TiO2(ETL)/CH3NH3PbBr3/Cu2O(HTL)/CdS(隧道结),/CdS(窗口层)/CdTe串联太阳能电池的效率为29.5%。设计这种结构是为了提高太阳能电池在温度升高时的稳定性,这对钙钛矿太阳能电池(PSC)的商业可行性很重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improving the efficiency and stability of Perovskite-CdTe tandem solar cell: A numerical simulation study with wx-AMPS
Organic and inorganic lead halide perovskites due to their low weight, high efficiency, and low cost, have played an important role in photovoltaic (PV) technology during the last decade. As an absorber layer, methylammonium lead bromide-based perovskite cells have a bandgap of 2.3 eV, which makes them compatible for tandem structures with CdTe solar cells with an energy gap of 1.45 eV. A low-cost device configuration model for the perovskite-CdTe tandem solar cell has been developed utilizing wx-AMPS simulation in this research. The single-junction perovskite solar cell has an efficiency of 21.8% and the single junction CdTe solar cell has an efficiency of 25.71%. The thickness and dopant concentration of absorber layers, i.e. perovskite and CdTe, the hole transport material (HTM), electron transport material (ETM), and the device temperature all have a role in influencing the solar cell output parameters and performance. The ideal CdTe and perovskite thicknesses were determined to be 4 µm and 6 µm, respectively at which the best efficiency was found. With an open-circuit voltage of 0.9997 V, a short circuit current of 33.91 mA/cm2, and a fill factor of 87 %, the efficiency of the FTO(TCO)/TiO2(ETL)/CH3NH3PbBr3/Cu2O(HTL)/CdS(Tunnel Junction),/CdS (Window layer)/CdTe tandem solar cell is 29.5%. This structure has been designed to improve the stability of the solar cell when the temperature rises, which is important for the commercial viability of perovskite solar cells (PSC).
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