纳米复合材料:制造、微观结构表征和力学测试

Petar Dotchev, Seyed Hamid Reza Sanei, E. Steinmetz, Jason J. Williams
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引用次数: 4

摘要

碳纳米管(CNT)具有优异的热学、电学和机械性能。虽然通过在聚合物基体中添加碳纳米管可以很容易地提高导热性和导电性,但必须研究其对机械性能的后续影响。本研究采用注射成型工艺制备纳米复合材料样品。将MWCNT浓度为15 wt.%的多壁碳纳米管(MWCNT)母粒用PA 6/6颗粒稀释,以产生5种不同的碳纳米管浓度,从3 wt.%到3 wt.%的增量。制备了整齐的聚合物样品作为对照样品。机械性能,如杨氏模量,拉伸强度和伸长率被确定,看看碳纳米管含量对整体性能的影响。利用扫描电镜(SEM)图像评价碳纳米管在聚合物相中的均匀分布。结果表明,随着碳纳米管含量的增加,刚度增加,但强度增加达到6 wt.%左右的阈值,超过该阈值强度下降。结果表明,碳纳米管的加入显著降低了聚合物的伸长率。伸长率从纯碳纳米管样品的平均190%下降到15 wt.%碳纳米管含量样品的5%。这种伸长率的降低可能使聚合物不适合其设计的应用。这项研究的结果表明,提高聚合物的热学和电学性能不会不牺牲机械性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nanocomposites: Manufacturing, Microstructural Characterization and Mechanical Testing
Carbon Nanotubes (CNT) offer exceptional thermal, electrical and mechanical properties. While an increase in thermal and electrical conductivity can be readily achieved by addition of CNT to a polymer base, the subsequent effect on mechanical properties must be investigated. In this study, nanocomposite samples were manufactured using injection molding process. Multiwall Carbon Nanotube (MWCNT) masterbatch with 15 wt.% MWCNT concentrations were diluted with PA 6/6 pellets to create five different CNT concentration ranging from 3 wt.% in 3 wt.% increments. The neat polymer sample was also manufactured as a control specimen. Mechanical properties such as Young’s modulus, Tensile strength and elongations were determined to see the effect of CNT content on overall properties. Scanning Electron Microscopy (SEM) images were used to evaluate the uniform distribution of CNT in the polymer phase. The results showed that the stiffness increased as the CNT content increased, however, the increase in strength reached a threshold value around 6 wt.% beyond which the strength decreased. It was observed that the elongation decreased significantly by addition of CNT into the polymer. The elongation dropped from an average of 190% for the neat sample to 5% for 15 wt.% CNT content sample. Such decrease in elongation might render the polymer unsuitable for the application it has been designed for. The findings of this study show that improving thermal and electrical properties of polymers does not come without a sacrifice on mechanical properties.
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