PbTiO3-CdS纳米复合材料的制备及其微观结构和光催化性能

Mingdong Xu, Wenqiang Li, Shunguo Liu, Zhang Tao, S. Yin, S. Lai
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引用次数: 1

摘要

为了探究铁电表面对半导体氧化物结构和性能的影响,以单晶钙钛矿PbTiO3纳米片为衬底,通过简单的水热法调控CdS纳米晶体的生长。通过组成设计,制备了一系列不同负载浓度的PbTiO3-CdS纳米复合材料,并对其微观结构和光催化性能进行了系统分析。研究表明,在所制备的产物中,CdS纳米粒子选择性地生长在PbTiO3纳米片表面,其形貌受PbTiO3纳米片暴露表面的影响。PbTiO3衬底与CdS纳米颗粒之间存在明显的界面。初始反应物的浓度和水热反应的时间对CdS的晶体形态也有显著影响。光催化研究表明,制备的PbTiO3-CdS纳米复合材料对10 mg/L罗丹明B水溶液具有显著的降解效果。降解效率随cd加载浓度的增加而增加。当降解10 mg/L罗丹明B水溶液时,质量分数为3%的PbTiO3-CdS样品在120 min内可达到72%的降解率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation of PbTiO3-CdS nanocomposite material and its microstructure and photocatalytic properties
In order to explore the influence of the ferroelectric surface on the structure and properties of semiconductor oxides, the growth of CdS nanocrystals was regulated and controlled by taking single-crystal perovskite PbTiO3 nanosheets as the substrate through a simple hydrothermal method. Through composition design, a series of PbTiO3-CdS nanocomposite materials with different loading concentrations were prepared, and their microstructure and photocatalytic properties were systematically analyzed. Studies show that in the prepared product, CdS nanoparticles selectively grow on the surfaces of PbTiO3 nanosheets, and their morphology is affected by the exposed surfaces of PbTiO3 nanosheets. There is a clear interface between the PbTiO3 substrate and CdS nanoparticles. The concentration of the initial reactant and the time of hydrothermal reaction also significantly affect the crystal morphology of CdS. Photocatalysis studies have shown that the prepared PbTiO3-CdS nanocomposite material has a significant degradation effect on 10 mg/L of Rhodamine B aqueous solution. The degradation efficiency rises with the increase of CdS loading concentration. When degrading 10 mg/L Rhodamine B aqueous solution, the PbTiO3-CdS sample with a mass fraction of 3% can reach a degradation rate of 72% within 120 min.
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