木质纤维素生物质热解动力学参数的测定

María del Rosario Baray-Guerrero, María Cecilia Valles-Aragón, Myrna Concepción Nevarez-Rodriguez, Carlos Manjarrez-Domínguez
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引用次数: 0

摘要

过去几十年来,人们对可再生能源和环境的兴趣大大增加,在能源效率、创造可持续技术和减少碳足迹方面作出了重大努力。因此,经济、高效地利用生物质是人们感兴趣的问题,对其进行研究和分析是必要的。本文采用非等温热重法测定了苹果残渣的活化能(Ea)和指数前因子(A)等动力学参数,并对微分法和最大速度法的数学模型进行了处理,并进行了活化能分布。活化能的计算有助于了解热分解发生的方式(如果有一个或多个过程,以及它们发生的转换范围),通过动力学模型提供的特征动力学常数,可以识别材料释放的气体种类,从而研究这种分解发生的过程
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Determinación de los parámetros cinéticos de la pirolisis de la biomasa lignocelulosica
Over the past decades, interest in renewable energy and the environment has grown considerably, with a significant effort being made in the field of energy efficiency, the creation of sustainable technologies and the reduction of the carbon footprint. Therefore, the use of biomass in an economical and efficient way is of interest, and its study and analysis becomes necessary. In this work, kinetic parameters such as activation energy (Ea) and preexponential factor (A) were determined for apple residues using the non-isothermal thermogravimetric method and treating the data obtained under the models mathematicians of the differential method and the maximum speed method, and additionally performing the activation energy distribution. The calculation of the activation energy helped to see the way in which thermal decomposition takes place (if there are one or more processes and in what range of conversions they occur), through the characteristic kinetic constants provided by the kinetic models, allowed to identify the gaseous species emitted by the material, and thus study the processes through which such decomposition occurs
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