氨基苯及其衍生物合成单偶氮分散染料的紫外和红外表征

J. Obi, Paul Chukwudi Osunwa
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引用次数: 1

摘要

研究了氨基苯及其衍生物在单偶氮分散染料合成中的应用前景。染料是通过氨基苯及其衍生物的重氮化,再与水杨酸偶联合成的。对合成的染料进行了紫外和红外表征,染料在甲醇、乙醇和乙酸乙酯中的紫外-可见吸收光谱表明,染料在电磁波谱的可见区有吸收带,并且染料的λmax随溶剂极性的增加而增加。FTIR表征表明,苯酚中存在C - O,胺中存在C - N和N - H,烷烃中存在C - H,硝基化合物中存在N = O,醇中存在- OH,染料的结构表明存在显色、异色和偶氮基团,这可能有助于解释染料具有优异显色性的原因。该染料对尼龙、羊毛、聚酯和棉花的染色和牢度性能表明,该染料在纺织工业中具有重要的商业价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
UV and IR Characterization of Monoazo Disperse Dyes Synthesized from Aminobenzene and its Derivatives
The potential of amino benzene and its derivatives in the synthesis of monoazo disperse dyes was studied. The dyes were synthesized by the diazotization of amino benzene and its derivatives and subsequent coupling with salicylic acid. The synthesized dyes were subjected to UV and IR characterization and the UV-VIS absorption spectra of the dyes in methanol, ethanol and ethyl acetate revealed that the dyes have absorption bands within the visible region of the electromagnetic spectrum and that the λmax of the dyes increases with increase in polarity of the solvents. The FTIR characterization of the dyes revealed the presence of C – O from phenol, C – N and N – H from amines, C – H from alkane, N = O from nitro compounds and – OH from alcohol and the proposed structures of the dyes revealed the presence of chromophoric, auxochromic and azodic groups which may help to explain why the dyes have excellent colourations. The dyeing and fastness properties of the dyes on nylon, wool, polyester and cotton revealed that the dyes will have commercial importance within the textile industries.
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