聚丙烯、乙烯-丙烯-二烯单体和氧化镁在PP共混纳米复合材料中的结构研究

N. A. Johari, K. Y. Lau, Z. Abdul-Malek, Mona Riza Mohd Esa, C. W. Tan, R. Ayop
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引用次数: 0

摘要

在电介质领域,聚丙烯(PP)最近被认为是交联聚乙烯(XLPE)的合理替代品,因为PP在150°C的热应力下具有高耐久性的优势,而且与XLPE相比,它易于回收。然而,高压电缆绝缘不能从PP挤出,因为它比XLPE更硬。与XLPE相比,PP在室温下具有较低的导热系数,这通常会导致较差的介电特性。因此,为了改变PP的物理和电学性能,需要对其进行改变。该研究建议将PP与EPDM共混,以获得整体刚度较小的PP共混物。工作包括表征原料的结构和热行为,包括PP, EPDM和氧化镁(MgO)。采用热重分析(TGA)、傅里叶变换红外光谱(FTIR)和差示扫描量热法(DSC)对PP、EPDM和MgO进行了表征。结果表明,所制备的材料均具有较好的热稳定性,适于制备聚丙烯共混纳米复合材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Structure of Polypropylene, Ethylene-Propylene- Diene-Monomer and Magnesium Oxide for the Formulation of PP Blend Nanocomposites
In the realm of dielectrics, polypropylene (PP) has lately been suggested as a reasonable replacement for cross-linked polyethylene (XLPE) due to PP's advantageous characteristics of high durability under heat stress of 150 °C and its ease of recycling when compared to XLPE. Nevertheless, high-voltage cable insulation cannot be extruded from PP because it is stiffer than XLPE. When compared to XLPE, PP has a lower thermal conductivity at room temperature, which would normally lead to poorer dielectric characteristics. As a result, PP needs to be changed in order to change both its physical and electrical properties. This investigation suggested PP and ethylene-propylene-diene monomer (EPDM) to be blended to create a PP blend with less overall stiffness. The work included characterizing the structure and the thermal behavior of the raw materials including PP, EPDM, and magnesium oxide (MgO). Several investigations involving thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC) were used to characterize the PP, EPDM, and MgO. The results showed that all the materials are thermally stable and appropriate for formulating PP blend nanocomposites.
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