柴油在氧化和贮存条件下的润滑稳定性评价

D. Nelyubov, J. SherbakovP., A. V. Chernisheva, V. A. Gubareva, A. O. Shatsky
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引用次数: 0

摘要

本文研究并定义了柴油氧化的最佳参数,以评价柴油在贮存条件下的润滑稳定性。在对原方法参数进行临界分析的基础上,修正了氧化燃料的体积、与燃料接触的催化活性金属的类型以及燃料-金属与燃料-空气接触方。这些修正被允许增加柴油在氧化时化学成分变化的充分性,以达到相同的储存条件变化。研究发现,使用铜作为催化活性材料的储罐,增加了羰基和羧基氧化产物的出现,减少了羟基氧化产物的出现,而羟基氧化产物的出现不足以反映柴油在钢皮中的化学变化。在对3个柴油样品进行调查的基础上发现,通过所建立的方法,可以预测柴油在贮存10个月后至少2、4和6小时的氧化,并对氧化样品的润滑能力进行估计。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Estimation of Lubrication Stability of Diesel Fuels under the Oxidation and Storage Conditions
The paper is given to investigation and definition of optimal parameters of oxidation of diesel fuels for the purpose of estimation its lubrication stability under the storage conditions. On the foundation of critical analyze of previous method’s parameters it were corrected the volume of oxidating fuel, the type of catalyze-active metal, which is contacting the fuel and also the fuel-metal and fuel-air contact-square. These corrections are allowed to increase the adequacy of chemical composition changes of diesel fuel at the oxidation to the same changes at the storage conditions. It was found that using the cuprum as the catalyze-active material of storage tanks increases the appearance of carbonyl and carboxyl oxidation products and decreases the appearance of hydroxyl oxidation products that is not adequately the chemical changes of diesel fuels while its storage in steel tare. On the foundation of three samples of diesel fuel investigation was found that decreasing of lubrication ability of diesel fuel at its storage for the 10 months could be forecasted by its oxidation via the developed method at least of 2, 4 and 6 hours with the following estimation lubrication ability of oxidated samples.
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