可持续的多产品二氧化碳捕获系统

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摘要

目前,我们正面临着几个严重的问题,包括疾病、气候变化、经济和战争。其中,为了保护子孙后代,这些问题亟待解决。最近,我们开发了一种基于使用NaOH和CaCl2等化合物的创新二氧化碳固定和储存方法,以防止气候危机。本文通过电解NaCl溶液或海水,使生成的NaOH与CO2反应。与二氧化碳反应的胺也被检查。此外,用海水代替CaCl2溶液生产CaCO3。虽然胺目前用于从废气中捕获二氧化碳,但胺-二氧化碳复合溶液的热处理是释放二氧化碳的必要条件。热处理需要能量,最终产生二氧化碳并诱导有机胺的降解。然而,在胺或氢氧化钠溶液中捕获的二氧化碳很容易通过酸化含有二氧化碳的溶液释放出来。此外,HCl还能从碳酸盐岩、Ca(OH)2、Mg(OH)2和mMgCO3·Mg(OH)2·nH2O以及矿物碳酸盐岩、CaCO3和MgCO3中释放CO2。这种从胺-二氧化碳复合物、碳酸盐和矿物碳酸盐中释放捕获的二氧化碳的简单方法对于获得纯二氧化碳作为原始材料的额外用途至关重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Sustainable System for CO2 Capturing with Multiple Products
Currently, we are facing several serious issues, including diseases, climate change, economics, and wars. Among them, which needs to be resolved imminently to protect the future generations. Recently, we developed an innovative CO2 fixation and storage method based on the use of chemical compounds such as NaOH and CaCl2, to prevent the climate crisis. Herein, the electrolysis of a NaCl solution or seawater was performed to make the resultant NaOH react with CO2. Amines that react with CO2 were also examined. Moreover, seawater was used to produce CaCO3 rather than the CaCl2 solution. Although amines are currently used to capture CO2 from exhaust gases, the thermal treatment of the amine–CO2 complex solution is necessary to release CO2. Thermal treatment requires energy that eventually produces CO2 and induces the degradation of organic amines. However, the CO2 captured in the amine or NaOH solution was released easily by acidifying the CO2-containing solutions. Moreover, HCl could release CO2 from hydro carbonates, Ca(OH)2, Mg(OH)2, and mMgCO3·Mg(OH)2·nH2O, as well as from mineral carbonates, CaCO3 and MgCO3. This simple method of releasing the captured CO2 from the amine–CO2 complexes, hydro carbonates, and mineral carbonates is crucial to obtain pure CO2 for additional usage as an original material.
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