大豆生物柴油在柴油循环发动机上的生产、表征及试验

S. C. P. Gonçalves, M. C. L. Souza, Joaquim Teixeira de Assis, J. Egusquiza, S. Braga, N. O. Tapanes
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引用次数: 1

摘要

通过热分析和粘度研究了氢氧化钠催化大豆油与无水乙醇酯交换反应制备生物柴油的特性及其热氧化稳定性。分析了20℃时的密度、硫含量、十六烷值、碳渣、碘指数、酸度、硫酸盐灰分、甘油和未反应脂肪酸的总含量。以甘油三酯与无水乙醇的摩尔比为2/1,催化剂用量为1%,温度为60℃,在耐热玻璃反应器中以乙醇为原料合成生物柴油。反应结束后,分离相,去除甘油。用0.1M HCl溶液在~ 70℃下洗涤生物柴油。理化分析表明,生物柴油各项参数均符合ANP技术标准要求。从所生产的生物柴油中,分别以2、5、10、15、20和30%的比例与柴油制成二元混合物。目的是研究柴油循环发动机中与涡流测力计耦合的混合物的行为。本研究对柴油发动机中燃烧生物柴油的混合燃料进行了分析,并与纯柴油进行了参数比较:消耗、效率、性能、扭矩和功率。结果表明,当混合量为20%时,其性能与纯柴油相当。对于掺量为30%的混合气,扭矩和功率明显下降,耗油量略有增加。结果表明,大豆油生物柴油是一种可再生、环保的燃料,其含量为2% ~ 30%,适合作为柴油循环发动机的替代燃料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
PRODUCTION CHARACTERIZATION AND TESTING OF SOYBEAN BIODIESEL IN A DIESEL CYCLE ENGINE
The characteristics of the biodiesel produced by the transesterification reaction of soybean oil with anhydrous ethanol, catalyzed by sodium hydroxide and its thermo-oxidative stability, were investigated by thermal analysis and viscosity. It was analyzed density at 20 °C, sulfur content, cetane number, carbon residue, iodine index, acidity, sulphated ash, the total content of glycerin and unreacted fatty acids. The synthesis of biodiesel via ethanolic processed in a Pyrex glass reactor with 2/1 molar ratio triglyceride/anhy-drous ethanol and 1% of catalyst, 60 °C. After the reaction, the phases were separated and glycerin was removed. The biodiesel was washed with 0.1M HCl solution, at ~ 70 oC for neutralization. The physicochemical analysis, all parameters for biodiesel met the requirements of the ANP Technical Standards. From the produced biodiesel, binary mixtures were made with diesel in the proportions of 2, 5, 10, 15, 20 and 30%. The objective was to study the behavior of mixtures in a diesel cycle engine coupled to a dynamometer of Eddy Current. In this study of burning biodiesel blends in diesel engine were analyzed and compared with pure diesel parameters: consumption, efficiency, performance, torque and power. The results showed that the mixtures had very similar properties and performance to pure diesel by mixing 20%.  To the mixture with 30% there has been a significant drop in torque and power and slight increase in consumption. Thus, it was shown that soybean oil biodiesel, mixtures of 2% to 30%, is applicable as an alternative fuel aptly, for the diesel cycle engines, because it is a renewable and environmentally friendly fuel.
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