低聚醚甲基丙烯酸酯中相变的声光研究

R. Mervinskii, Jan Kityk, M. Makowska-Janusik, J. Filipecki, J. Straube, Josyp Yatczyszyn
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引用次数: 0

摘要

研究了不同化学成分的聚甲基丙烯酸乙酯光聚合物的声光质量系数随温度的变化。发现芳香环的增加导致声光质量系数M的增加,这是在我们观察到C = O化学键之间距离的影响之后。在80 ~ 100℃以下,M随温度的降低而增加K。M的最大值在4.2 K处达到。所得数据与以往光学二次谐波产生的研究结果吻合较好。揭示了外电场对光聚合物声光性能的重要影响。我们认为它反映了非中心准晶体的重要作用,它们对压电光学常数有贡献。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Acousto-optical investigations of the phase transitions in the oligoethermetacrylates
We investigated the changes of acousto-optical quality coefficients in olygoethermethacrylate photopolymers of the different chemical contents from temperature. It was revealed that increasing of the aromatic's rings leads to increasing of the acousto-optical quality coefficients M, and only after we have observed the influence of the distances between the C equals O chemical bonds. We also found an increasing of M with the decrease of the temperature below the 80...100 K. The maximal value of the M reaches its value at 4.2 K. The data obtained are in good agreement with previous investigations of the optical second harmonic generation. An essential influence of external electric field on the acousto-optical properties of the mentioned photopolymers was revealed. In our opinion it reflects an essential role of the acentrical quasicrystallines, which give contributions into the piezo-optical constants.
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