层合橡胶手套制造工艺粘接能力的提高

Nilusha Lakmali Rajashilpa, S. Jayasinghe, Lahiru Tharanga
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引用次数: 0

摘要

作为一种乳胶基产品,层压橡胶手套用于重型用途和建筑行业。在手套的手掌区域粘贴准备好的层压橡胶片,该橡胶片由凯夫拉纤维制成。低附着力导致层压橡胶片从织物中分离。本研究的主要目的是在制造过程中提高层合橡胶手套的粘附能力。本研究包括三个主要实验(I, II和III)。在每个实验中应用修改后的粘合剂之前,根据通用的粘合剂配方和现有的工艺线进行初步实验。实验一是为了确定用于将橡胶片粘贴到织物上的粘合剂共混物在最高粘合水平时,二级溶剂SBP的准确体积、准确的粘度值和总固含量(TSC)值。实验二对现有工艺线进行改造,通过改变前期试验确定的平滑、成熟和高压灭菌固化/硫化关键工艺步骤的条件,提高层压橡胶手套的粘附能力。实验三在实验二结果的基础上,在最适宜的固化温度和固化时间组合下,通过改变对胶粘剂粘附能力影响最大的增粘剂(木树脂)的用量来改变胶粘剂配方。实验I、II和III每个样品下制备的所有完成重复均采用拉伸测试仪进行粘附性测试,并用MINITAB 16统计软件对数据进行分析。根据实验的最终结果,新型胶粘剂的共混物应由一次溶剂与SBP的胶粘剂按1:2的比例组成,在胶粘剂配方总量的基础上,加入14%的木材树脂作为增粘剂,以提高胶粘剂的附着力,生产工艺路线应由两轮平滑组成,熟化前的休息时间为24小时。固化温度为1200Ϲ,在高压灭菌器中固化时间为90分钟,以提高层压橡胶手套的粘附能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improving of Adhesion Ability of Laminated Rubber Glove Manufacturing Process
As a latex based product, the laminated rubber glove is used for heavy duty purposes and the construction industry. Prepared laminated rubber sheet is pasted on the palm area of the glove, which is made of Kevlar fabric. The low adhesion causes the laminated rubber sheet to separate from the fabric. The main objective of this research is improving the adhesion ability of laminated rubber glove in the manufacturing process. This study consisted of three main experiments (I, II and III). Preliminary experiments were done based on a common formula of adhesive and the existing process line before applying the modifications in each experiment. Experiment I was carried out to find out the accurate volume of secondary solvent, called SBP, to give the best adhesion, accurate viscosity value, and the Total Solid Content (TSC) value during the highest adhesion level of the adhesive blend which is used to paste the rubber sheet to the fabric. Experiment II was conducted to modify the existing process line by changing the conditions of critical process steps identified by preliminary tests, which are smoothing, maturing and curing/vulcanization in an autoclave to increase the adhesion ability of laminated rubber glove. Experiment III was done to change the adhesive formula by changing the tackifier (wood resin) amount which is the most influential ingredient to enhance the adhesion ability of adhesive under most appropriate combinations of the curing temperature with curing time, based on the results of experiment II. Adhesion tests were done by using Tensile Tester for all completed replicates prepared under each sample of experiments I, II and III, and data were analyzed by using MINITAB 16 statistical software. According to the end result obtained through these experiments, the new adhesive blend should consist of the adhesive compound with primary solvent to SBP in the ratio 1:2, with the addition of 14% of wood resin as tackifier, based on the total for the adhesive formula, to improve the adhesion value, and the manufacturing process line should consist of two smoothing turns, a 24 hour maturing period as resting time before curing, and a curing temperature of 1200Ϲ with 90 minutes curing time in an autoclave to improve the adhesion ability of the laminated rubber glove.
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