加热和电阻对碳纳米管发射性能的影响

Sergey V. Bulyarskiy 1, Alexander A. Dudin 1, Alexander V. Lakalin 1, Andrey P. Orlov 1, Alexander A. Pavlov 1, Roman M. Ryazanov 2, Artemiy A. Shamanaev 2
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摘要

我们研究了串联电阻对碳纳米管阴极加热的影响,该阴极用于实现电子在真空中的场发射。实验采用镍钛薄膜催化剂(镍为4 nm /钛为10 nm),将单层多壁碳纳米管(MCNT)从CVD法生长的阵列中分离出来。阴极的加热导致热离子发射电流的出现。实验电压电流特性表现为热场发射引起的负电阻区。该电流随着电压的增加而强烈增加,并有助于冷发射极的退化。在计算阴极端面温度时,考虑了阴极加热和冷却现象的影响。我们开发了一种处理阴极发射伏安特性的方法,该方法依赖于场发射电流的数值计算,并将这些计算与实验进行比较。伏安特性模型考虑了碳纳米管的几何形状、性质、与催化剂的接触;热离子和场发射的加热和同时实现。通过计算可以确定许多重要的参数,其中包括热离子发射开始时的电压和电流,阴极温度分布,纳米管的电阻。从实验和理论上研究了碳纳米管的热离子发射现象。定义了这种类型发射发生的条件。研究结果可为碳纳米管发射极的退化提供理论依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of heating and resistance on emission properties of carbon nanotubes
We have studied the effect of the series resistance on the heating of the cathode, which is based on carbon nanotubes and serves to realize the field emission of electrons into the vacuum. The experiment was performed with the single multi-walled carbon nanotube (MCNT) that was separated from the array grown by CVD method with thin-film Ni-Ti catalyst (nickel 4 nm / Ti 10 nm). The heating of the cathode leads to the appearance of a current of the thermionic emission. The experimental voltage current characteristic exhibited the negative resistance region caused by thermal field emission. This current increases strongly with increasing voltage and contributes to the degradation of the cold emitter. The calculation of the temperature of the end of the cathode is made taking into account the effect of the phenomenon that warms up and cools the cathode. We have developed a method for processing of the emission volt-ampere characteristics of a cathode, which relies on a numerical calculation of the field emission current and the comparison of these calculations with experiments. The model of the volt-ampere characteristic takes into account the CNT’s geometry, properties, its contact with the catalyst; heating and simultaneous implementation of the thermionic and field emission. The calculation made it possible to determine a number of important parameters, among which the voltage and current of the beginning of thermionic emission, the temperature distribution along the cathode, the resistance of the nanotube. The phenomenon of thermionic emission from CNT’s was investigated experimentally and theoretically. The conditions of this type emission occurrence were defined. The results of the study could form the basis of theory of CNT emitter’s degradation.
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