新型光折变材料咔唑和联吡啶共聚物的研究进展

International Conference on Holography, Optical Recording, and Processing of Information Pub Date : 2006-05-20 DOI:10.1117/12.676785

D. Bogdał, M. Pajda, J. Pielichowski, A. Attias, J. Fave

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引用次数: 0

摘要

合成了以咔唑悬垂基团和联吡啶衍生物为侧链的新型丙烯酸酯共聚物，其中联吡啶衍生物为电光发色团，咔唑基为光导基团，共价连接在丙烯酸酯主链上。合成了2-{9-咔唑基)甲基丙烯酸乙酯(CEM)和2-甲基丙烯酸2-{4,4'-二甲基-5'-[2-(5-甲基-噻吩-2-基)-乙烯]-[2,2']联吡啶基-5-基}乙酯(BiPy)，共聚得到(99:1)、(98:2)和(92:8 mol/mol) CEM/BiPy共聚物。研究了该共聚物在二氧六烷溶液中的光致发光性能。

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Development of carbazole and bipyridine copolymers as novel photorefractive materials

Novel acrylate copolymer with carbazole pendant groups and derivatives of bipyridine as side chains were synthesized, in which derivatives of bipyridine as electro-optic chromophores and carbazolyl as photoconductive moiety were covalently linked on the acrylate backbone. 2-{9-Carbazolyl)ethyl methacrylate (CEM) and 2-methyl-acrylic acid 2-{4,4'-dimethyl-5'-[2-(5-methyl-thiophen-2-yl)-vinyl]-[2,2']bipyridinyl-5-yl}-ethyl ester (BiPy) were synthesized and then copolymerized to give (99:1), (98:2), and (92:8 mol/mol) CEM/BiPy copolymers. Solutions of the copolymers in dioxane were examined for their photoluminescence properties.

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International Conference on Holography, Optical Recording, and Processing of Information

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