含双噻唑环的聚合物及其铜配合物的合成与性能

G. Xiong, H. Huang, Y. Zhou
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引用次数: 0

摘要

制备了聚合物(SAD)及其铜配合物,考察了反应温度和反应时间对收率的影响。采用红外光谱(IR)、元素分析和能谱分析(EDS)对其结构进行了表征,并通过热重差热分析(tg - dta)、导电性能测试和磁性能测试对其性能进行了分析。结果表明:在温度为100Â℃,反应6h后,SAD的最大产率为79.5%。磁滞回线表明,SAD为反铁磁体,而SAD- cu2 +为软铁磁体,其矫顽力场(HC)为66 Oe,剩余磁化强度(Mr)为0.00105 emu/g,饱和磁化强度为0.029 emu/g。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Properties of Polyer and its Cupric Complex Containing Bithiazole Rings
The polymer (SAD) and its cupric complex were prepared and the effects of the temperature and time of reaction on the yield were investigated. Their structures were characterized by IR, elemental analysis and EDS and their properties were analyzed by TGA-DTA, conductive property test and magnetic property test. The result indicated: discovered on the temperature of 100°C and reaction 6h later the maximum yield of SAD is 79.5%. Their hysteresis loops show that SAD is an antiferromagnet while SAD-Cu2+ is a soft ferromagnet, in which the observed coercive field (HC) is 66 Oe, the remnant magnetization (Mr) is 0.00105 emu/g and the saturation magnetization 0.029 emu/g.
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