利沃夫地区泥炭沉积物中化学元素的分布

M. Yakovenko, Yu.V. Khokha, O. Lyubchak
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引用次数: 1

摘要

本文对利沃夫地区泥炭中化学元素的含量进行了研究和解释。众所周知,泥炭具有明显的物理吸附和化学吸附能力,因此它能够积累大量的金属,包括危险的重金属、有毒的和放射性的。泥炭被用作能源原料,近年来被用作化学和制药工业的原料。因此,这种地球化学研究对广泛的工业和环境监测具有科学和应用的重要性。泥炭的施用范围直接取决于微量元素的浓度。找出了利沃夫地区泥炭低地类型的基本地球化学特征。与岩石圈、土壤和陆生植物相比,泥炭的元素含量总体上低于植被。亲石性Sr、Yb、Be、Ba、亲铁性Mo、Co和亲铜性Pb、Ag在乌克兰的岩石圈、土壤、植物灰烬和相对于背景值的土壤中与clarkes相比活跃富集。根据对利沃夫地区低地泥炭中微量元素含量的综合分析结果,鉴定出3种高浓度元素钼、锶和铅。微量元素浓度随分布深度和分布面积呈明显不均匀分布,Mo、Yb、Sr、Be、Co、Ag、Ba、Pb等微量元素指标相对岩石圈、土壤、植物灰分等均较高。泥炭与岩石圈、土壤和陆生植物元素的富集和分散规律的比较表明,泥炭具有自己特有的一套储集元素,具有特定的富集和分散规律。因此,泥炭具有明确的地球化学结构,使其区别于矿物土壤和岩石圈。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Distribution of chemical elements in peat deposits of the Lviv Region
The article is devoted to the study and interpretation of the content of chemical elements in peats of Lviv Region. It is known that peat has a pronounced ability to physical sorption and chemisorption, as a result it is able to accumulate a significant amount of metals, including dangerous – heavy, toxic and radioactive. Peat is used as an energy raw material, in recent years – as a raw material for the chemical and pharmaceutical industries. Thus, this geochemical research has scientific and applied importance for a wide range of industries and for environmental monitoring. The range of peat applications directly depends on the concentration of trace elements. The basic geochemical characteristics of peat lowland type in Lviv Region were found out. In general, the content of elements in the studied peat has concentrations lower than сlarkes in comparison with the lithosphere, soils and terrestrial plants. Lithophilic Sr, Yb, Be, Ba, siderophilic Mo, Co, and chalcophilic Pb, Ag are actively concentrated in comparison with clarkes in the lithosphere, soils, plant ashes and relative to background values in the soils of Ukraine. According to the results of a comprehensive analysis of the content of microelements in lowland peats of Lviv Region, three elements with high concentration were identified – Molybdenum, Strontium and Lead. Significant uneven distribution of microelement concentration with depth and area of distribution and high indicators of Mo, Yb, Sr, Be, Co, Ag, Ba, Pb relative to clarkes of lithosphere, soils, plant ash, etc. have been established. Comparison of patterns of accumulation and scattering of elements in peat with lithosphere, soils and terrestrial plants shows that peat is characterized by its own specific set of storage elements, there are specific patterns of accumulation and scattering of elements. Thus, peat has a clear geochemical structure that distinguishes them from mineral soils and lithosphere.
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