哈拉雷固体废物管理方案的富营养化影响潜力

Trust Nhubu, C. Mbohwa, E. Muzenda
{"title":"哈拉雷固体废物管理方案的富营养化影响潜力","authors":"Trust Nhubu, C. Mbohwa, E. Muzenda","doi":"10.1201/9780429289798-57","DOIUrl":null,"url":null,"abstract":"Six municipal solid waste management options (A1– A6) in Harare were developed and analyzed for their eutrophication impact potentials under the Life Cycle Assessment (LCA) methodology. All the options started with waste collection and transportation to a centralized waste treatment centre where a combination of various municipal solid waste management and treatment methods were considered under the different options. Results show that landfilling and material recovery for reuse and recyle are the only MSW management processes that contributes to negative eutrophication potential giving options that had landfilling (A1, A4 and A6) an overall edge. The doubling of recycling rate under A5 and increasing it to atleast 25% under A6 result in below zero eutrophication impact potentials. Results reveal that anaerobic digestion and incineration contribute to increased eutrophication potential under all the options they were considered hence need for further assessments considering other impact categories to determine the most sustainable option. water to Harare and Chitungwiza. The eutrophication of Lake Chivero is not a welcome development considering its threats to the availability of potable water for Harare and Chitungwiza. It has led to increased costs for potable water production partly contributing to the erratic potable water supplies in most parts of Harare currently being experienced. Bauman and Tillman (2004) described eutrophication as a phenomenon with the potential of affecting terrestrial and aquatic ecosystems due to nutrient enrichment namely Nitrogen (N) and phosphorus (P) in water systems. The MSW generated in Harare has an excess of biowaste constituting over 60% (UNEP, 2011) hence if improperly managed can lead to nutrient enrichment in water bodies leading to eutrophication. Magadza (2003) reported that the breakdown in hygiene has led to nutrient rich surface run-off from uncollected MSW and illegal MSW dumps significantly contributing to Lake Chivero eutrophication. The design and development of sustainable MSW management option for Harare becomes a necessity to address the human health challenges and availability of freshwater that guarantee the long term consistent supply of potable water for Harare residents. Life Cycle Assessment (LCA) has proven to be an effective tool for designing and developing sustainable and integrated MSW management as it aids the assessment of environmental loads of different MSW options (Miliute and Kazimieras Staniškis, 2010; Rives et al., 2010; Koci and Trecakova, 2011; Stucki et al., 2011; Gunamantha and Sarto, 2012; Fernández-Nava et al., 2014). Therefore, this work is an LCA based comparative study to assess the eutrophication impact potential of different MSW management options for Harare. The objective being to determine the option with the least eutrophication impact potential in light of the reported eutrophic status of the potable water sources in Harare. 2 MATERIALS AND METHODS 2.1 Description of study area The study area is Harare the capital city of Zimbabwe with an estimated population of 1,485,231 (Zimstat, 2013) and covering an area of 960.6 km 2 at an altitude of 1483 m. An estimate of 325,266 tons of MSW is generated per year (Mshandete and Parawira, 2009, Muchandiona et al., 2013, Pawandiwa, 2013, Mbiba, 2014, Hoornweg and Bhada-Tata, 2012, Emenike et al., 2013) in Harare with 60% indiscriminately collected and dumped at Pomona dumpsite the only official dumpsite whose capacity is exhausted by 2020 (Chijarira, 2013). The waste that is generated in Harare is estimated to have average composition of 42% biodegradable waste, 33% plastics, 8% metals, 14% paper and 3% glass (Nyanzou and Steven, 2014, Mudzengerere and Chigwenya, 2012). Harare sits upstream and on the catchment of its potable water source (Lake Chivero) making all the MSW management activities in Harare contributing towards the reported super eutrophic levels of the Lake. Underground water in Harare has also been reported to have been contaminated with nutrients, metals, acids and coliform bacteria (Muchandiona et al., 2013, Love et al., 2006, Eukay and Kharlamova, 2014, Kharlamova et al., 2016). 2.2 MSW management option 1 – A1 The entire 325,266 tons of MSW generated per year in Harare is indiscriminately collected before any treatment (both biodegradable and nonorganic MSW) and landfilled in a sanitary landfill with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.3 MSW management option 2 – A2 The entire 325,266 tons of MSW generated per year in Harare is indiscriminately collected before any treatment (both biodegradable and nonorganic MSW) and incinerated in an incinerator with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.4 MSW management option 3 – A3 Biodegradable MSW generated amounting to 136,612 tons is digested in an anaerobic digester producing biogas. The biogas is fed into Combined Heat and Power (CHP) generation plant to produce heat and electricity. The remaining non-biodegradable fraction 188,654 tons mixed bag MSW (107,338 tons plastics, 26,021 tons metals, 45,537 tons paper and 9,758 tons glass) is incinerated as in A2 with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.5 MSW management option 4 – A4 As in A3 difference being that the remaining non-biodegradable fraction 188,654 tons mixed bag MSW (107,338 tons plastics, 26,021 tons metals, 45,537 tons paper and 9,758 tons glass) is landfilled as in A1 with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.6 MSW management option 5 – A5 20% of the non-biodegradable MSW amounting to 37,731 tons (21,468 tons plastics, 5,204 tons metals, 9,107 tons paper and 1,952 tons glass) are recovered in the material recovery facility or sorting plant for reuse and recycling. The 80% non-biodegradable MSW remaining from the material recovery facility amounting to 150,923 tons (85,870 tons plastics, 20,817 tons metals, 36,430 tons paper and 7,806 tons glass) is incinerated as in A2 with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.7 MSW management option 6 – A6 20% of the non-biodegradable MSW amounting to 37,731 tons (21,468 tons plastics, 5,204 tons metals, 9,107 tons paper and 1,952 tons glass) are recovered in the material recovery facility or sorting plant for reuse and recycling. The 80% non-biodegradable MSW remaining from the material recovery facility amounting to 150,923 tons (85,870 tons plastics, 20,817 tons metals, 36,430 tons paper and 7,806 tons glass) is landfilled as in A1 with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.8 Life Cycle Assessment The eutrophication impact potential for the six MSW management options was estimated using the LCA methodology with the ISO 14040 standards applied as the basis of the LCA. Simapro version 8.5.2 analyst software and update 852 database were used for the LCA under the ReCiPe 2016 v1.02 endpoint method. The yearly MSW generation of 325,266 tons was used as the functional unit (Fernández-Nava et al., 2014, Beigl and Salhofer, 2004, Cherubini et al., 2009). Waste collection and transportation, landfilling, incineration, anaerobic digestion material recovery, CHP generation, landfill leachate treatment and incineration flue gas treatment were the considered life cycle stages. 3 RESULTS AND DISCUSSIONS Figure 1 shows the LCIA results with regards to the eutrophication impact potential of the six MSW management options. MSW management options A1and A4 leads to reduced extinction rate of species thus reduced eutrophication impact potential with A2 to A6 bringing about an increased species extinction rates. Table 1: Process Contributions to eutrophication Process MSW management options","PeriodicalId":228868,"journal":{"name":"Wastes: Solutions, Treatments and Opportunities III","volume":"3 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Eutrophication impact potential of solid waste management options in Harare\",\"authors\":\"Trust Nhubu, C. Mbohwa, E. Muzenda\",\"doi\":\"10.1201/9780429289798-57\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Six municipal solid waste management options (A1– A6) in Harare were developed and analyzed for their eutrophication impact potentials under the Life Cycle Assessment (LCA) methodology. All the options started with waste collection and transportation to a centralized waste treatment centre where a combination of various municipal solid waste management and treatment methods were considered under the different options. Results show that landfilling and material recovery for reuse and recyle are the only MSW management processes that contributes to negative eutrophication potential giving options that had landfilling (A1, A4 and A6) an overall edge. The doubling of recycling rate under A5 and increasing it to atleast 25% under A6 result in below zero eutrophication impact potentials. Results reveal that anaerobic digestion and incineration contribute to increased eutrophication potential under all the options they were considered hence need for further assessments considering other impact categories to determine the most sustainable option. water to Harare and Chitungwiza. The eutrophication of Lake Chivero is not a welcome development considering its threats to the availability of potable water for Harare and Chitungwiza. It has led to increased costs for potable water production partly contributing to the erratic potable water supplies in most parts of Harare currently being experienced. Bauman and Tillman (2004) described eutrophication as a phenomenon with the potential of affecting terrestrial and aquatic ecosystems due to nutrient enrichment namely Nitrogen (N) and phosphorus (P) in water systems. The MSW generated in Harare has an excess of biowaste constituting over 60% (UNEP, 2011) hence if improperly managed can lead to nutrient enrichment in water bodies leading to eutrophication. Magadza (2003) reported that the breakdown in hygiene has led to nutrient rich surface run-off from uncollected MSW and illegal MSW dumps significantly contributing to Lake Chivero eutrophication. The design and development of sustainable MSW management option for Harare becomes a necessity to address the human health challenges and availability of freshwater that guarantee the long term consistent supply of potable water for Harare residents. Life Cycle Assessment (LCA) has proven to be an effective tool for designing and developing sustainable and integrated MSW management as it aids the assessment of environmental loads of different MSW options (Miliute and Kazimieras Staniškis, 2010; Rives et al., 2010; Koci and Trecakova, 2011; Stucki et al., 2011; Gunamantha and Sarto, 2012; Fernández-Nava et al., 2014). Therefore, this work is an LCA based comparative study to assess the eutrophication impact potential of different MSW management options for Harare. The objective being to determine the option with the least eutrophication impact potential in light of the reported eutrophic status of the potable water sources in Harare. 2 MATERIALS AND METHODS 2.1 Description of study area The study area is Harare the capital city of Zimbabwe with an estimated population of 1,485,231 (Zimstat, 2013) and covering an area of 960.6 km 2 at an altitude of 1483 m. An estimate of 325,266 tons of MSW is generated per year (Mshandete and Parawira, 2009, Muchandiona et al., 2013, Pawandiwa, 2013, Mbiba, 2014, Hoornweg and Bhada-Tata, 2012, Emenike et al., 2013) in Harare with 60% indiscriminately collected and dumped at Pomona dumpsite the only official dumpsite whose capacity is exhausted by 2020 (Chijarira, 2013). The waste that is generated in Harare is estimated to have average composition of 42% biodegradable waste, 33% plastics, 8% metals, 14% paper and 3% glass (Nyanzou and Steven, 2014, Mudzengerere and Chigwenya, 2012). Harare sits upstream and on the catchment of its potable water source (Lake Chivero) making all the MSW management activities in Harare contributing towards the reported super eutrophic levels of the Lake. Underground water in Harare has also been reported to have been contaminated with nutrients, metals, acids and coliform bacteria (Muchandiona et al., 2013, Love et al., 2006, Eukay and Kharlamova, 2014, Kharlamova et al., 2016). 2.2 MSW management option 1 – A1 The entire 325,266 tons of MSW generated per year in Harare is indiscriminately collected before any treatment (both biodegradable and nonorganic MSW) and landfilled in a sanitary landfill with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.3 MSW management option 2 – A2 The entire 325,266 tons of MSW generated per year in Harare is indiscriminately collected before any treatment (both biodegradable and nonorganic MSW) and incinerated in an incinerator with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.4 MSW management option 3 – A3 Biodegradable MSW generated amounting to 136,612 tons is digested in an anaerobic digester producing biogas. The biogas is fed into Combined Heat and Power (CHP) generation plant to produce heat and electricity. The remaining non-biodegradable fraction 188,654 tons mixed bag MSW (107,338 tons plastics, 26,021 tons metals, 45,537 tons paper and 9,758 tons glass) is incinerated as in A2 with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.5 MSW management option 4 – A4 As in A3 difference being that the remaining non-biodegradable fraction 188,654 tons mixed bag MSW (107,338 tons plastics, 26,021 tons metals, 45,537 tons paper and 9,758 tons glass) is landfilled as in A1 with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.6 MSW management option 5 – A5 20% of the non-biodegradable MSW amounting to 37,731 tons (21,468 tons plastics, 5,204 tons metals, 9,107 tons paper and 1,952 tons glass) are recovered in the material recovery facility or sorting plant for reuse and recycling. The 80% non-biodegradable MSW remaining from the material recovery facility amounting to 150,923 tons (85,870 tons plastics, 20,817 tons metals, 36,430 tons paper and 7,806 tons glass) is incinerated as in A2 with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.7 MSW management option 6 – A6 20% of the non-biodegradable MSW amounting to 37,731 tons (21,468 tons plastics, 5,204 tons metals, 9,107 tons paper and 1,952 tons glass) are recovered in the material recovery facility or sorting plant for reuse and recycling. The 80% non-biodegradable MSW remaining from the material recovery facility amounting to 150,923 tons (85,870 tons plastics, 20,817 tons metals, 36,430 tons paper and 7,806 tons glass) is landfilled as in A1 with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.8 Life Cycle Assessment The eutrophication impact potential for the six MSW management options was estimated using the LCA methodology with the ISO 14040 standards applied as the basis of the LCA. Simapro version 8.5.2 analyst software and update 852 database were used for the LCA under the ReCiPe 2016 v1.02 endpoint method. The yearly MSW generation of 325,266 tons was used as the functional unit (Fernández-Nava et al., 2014, Beigl and Salhofer, 2004, Cherubini et al., 2009). Waste collection and transportation, landfilling, incineration, anaerobic digestion material recovery, CHP generation, landfill leachate treatment and incineration flue gas treatment were the considered life cycle stages. 3 RESULTS AND DISCUSSIONS Figure 1 shows the LCIA results with regards to the eutrophication impact potential of the six MSW management options. MSW management options A1and A4 leads to reduced extinction rate of species thus reduced eutrophication impact potential with A2 to A6 bringing about an increased species extinction rates. 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引用次数: 4

摘要

根据生命周期评估(LCA)方法,制定并分析了哈拉雷六个城市固体废物管理方案(A1 - A6)的富营养化影响潜力。所有的方案都是从废物收集和运输到一个集中的废物处理中心开始,在不同的方案下,综合考虑各种城市固体废物的管理和处理方法。结果表明,填埋和材料回收再利用和再循环是唯一有助于负富营养化潜力的城市生活垃圾管理过程,使填埋(A1, A4和A6)的选择具有整体优势。在A5条件下将回收率提高一倍,并在A6条件下将其提高到至少25%,导致富营养化影响潜值低于零。结果表明,厌氧消化和焚烧在所有考虑的方案下都有助于增加富营养化潜力,因此需要进一步评估,考虑其他影响类别,以确定最可持续的方案。向哈拉雷和奇通wiza供水。考虑到奇韦罗湖的富营养化威胁到哈拉雷和奇通维扎的饮用水供应,这不是一个受欢迎的发展。它导致饮用水生产成本增加,部分原因是目前哈拉雷大部分地区的饮用水供应不稳定。Bauman和Tillman(2004)将富营养化描述为一种由于水体中氮(N)和磷(P)等养分富集而可能影响陆地和水生生态系统的现象。哈拉雷产生的城市生活垃圾中有超过60%的生物垃圾(UNEP, 2011),因此,如果管理不当,可能导致水体中的营养物质富集,从而导致富营养化。Magadza(2003)报告说,卫生条件的破坏导致未收集的城市生活垃圾和非法倾倒的城市生活垃圾流入富含营养的地表,这对奇韦罗湖的富营养化起到了重要作用。为哈拉雷设计和制定可持续的都市固体废物管理备选办法已成为应对人类健康挑战和淡水供应的必要条件,淡水供应可保证哈拉雷居民长期稳定地获得饮用水。生命周期评估(LCA)已被证明是设计和开发可持续和综合城市固体废物管理的有效工具,因为它有助于评估不同城市固体废物选择的环境负荷(Miliute和Kazimieras Staniškis, 2010;Rives et al., 2010;Koci and treakova, 2011;Stucki et al., 2011;Gunamantha and Sarto, 2012;Fernández-Nava et al., 2014)。因此,本研究是一项基于LCA的比较研究,旨在评估不同城市生活垃圾管理方案对哈拉雷富营养化的影响潜力。研究的目标是根据哈拉雷饮用水水源的富营养化状况,确定具有最小富营养化影响潜力的方案。2材料和方法2.1研究区域描述研究区域是津巴布韦首都哈拉雷,人口估计为1,485,231 (Zimstat, 2013),覆盖面积为960.6 km 2,海拔1483米。据估计,哈拉雷每年产生325,266吨城市生活垃圾(Mshandete和Parawira, 2009年,Muchandiona等人,2013年,Pawandiwa, 2013年,Mbiba, 2014年,Hoornweg和Bhada-Tata, 2012年,Emenike等人,2013年),其中60%的垃圾被任意收集并倾倒在Pomona垃圾场,这是唯一一个到2020年容量将被消耗的官方垃圾场(Chijarira, 2013年)。据估计,哈拉雷产生的废物平均成分为42%的可生物降解废物,33%的塑料,8%的金属,14%的纸张和3%的玻璃(Nyanzou和Steven, 2014, Mudzengerere和Chigwenya, 2012)。哈拉雷位于其饮用水源(奇韦罗湖)的上游和集水区,使得哈拉雷的所有城市生活垃圾管理活动都导致了该湖报告的超富营养化水平。据报道,哈拉雷的地下水也被营养物质、金属、酸和大肠菌群污染(Muchandiona等人,2013年,Love等人,2006年,Eukay和Kharlamova, 2014年,Kharlamova等人,2016年)。2.2都市固体废物管理方案1 - A1哈拉雷每年产生的全部325,266吨都市固体废物在任何处理(包括可生物降解和非有机都市固体废物)之前都被不加区分地收集起来,并通过沼气回收和垃圾渗滤液处理填埋在卫生填埋场。回收的沼气被送入热电联产(CHP)电厂发电。2.3城市固体废物管理方案2 - A2哈拉雷每年产生的全部325,266吨城市固体废物在进行任何处理(包括可生物降解和非有机城市固体废物)之前被不加区分地收集起来,然后在焚化炉中进行焚烧,并进行能量回收、烟气处理和处理焚化炉底灰回收过程中产生的渗滤液。 考虑到国家道路基础设施的需要,焚烧炉底和粉煤灰作为道路建设的材料。2.4都市固体废物管理方案3 - A3产生的可降解都市固体废物达136,612吨,由厌氧沼气池消化产生沼气。沼气被送入热电联产(CHP)发电厂生产热能和电能。剩余的不可生物降解部分188,654吨混合袋生活垃圾(107,338吨塑料、26,021吨金属、45,537吨纸和9,758吨玻璃)按照A2进行焚烧,并进行能量回收、烟气处理和处理焚烧炉底灰回收过程中产生的渗滤液。考虑到国家道路基础设施的需要,焚烧炉底和粉煤灰作为道路建设的材料。2.5都市固体废物管理方案4 - A4与A3的不同之处在于,剩余的不可生物降解部分188,654吨混合袋都市固体废物(107,338吨塑料、26,021吨金属、45,537吨纸张和9,758吨玻璃)将按照A1的方法进行沼气回收和堆填渗滤液处理。回收的沼气被送入热电联产(CHP)电厂发电。2.6都市固体废物管理方案5 - A5不可生物降解的都市固体废物中,有20%(共37,731吨,其中包括21,468吨塑料、5,204吨金属、9,107吨纸张和1,952吨玻璃)在物料回收设施或分拣厂回收,以作再用和循环再造。材料回收设施中剩余的80%不可生物降解的生活垃圾(150,923吨,其中包括85,870吨塑料、20,817吨金属、36,430吨纸张和7,806吨玻璃)在A2中进行焚烧,同时进行能源回收、烟气处理和处理焚烧炉底灰回收过程中产生的渗滤液。考虑到国家道路基础设施的需要,焚烧炉底和粉煤灰作为道路建设的材料。2.7都市固体废物管理方案6 - A6不可生物降解的都市固体废物中,有20%(共37,731吨,其中包括21,468吨塑料、5,204吨金属、9,107吨纸张和1,952吨玻璃)在物料回收设施或分拣厂回收,以作再用和循环再造之用。从物料回收设施中剩余的80%不可生物降解的都市固体废物,共150,923吨(85,870吨塑料,20,817吨金属,36,430吨纸张和7,806吨玻璃),在沼气回收和垃圾渗滤液处理的情况下,按A1填埋。回收的沼气被送入热电联产(CHP)电厂发电。2.8生命周期评估六种都市固体废物管理方案的富营养化潜在影响,是采用生命周期评估方法,并以ISO 14040标准作为生命周期评估的基础。在ReCiPe 2016 v1.02端点方法下,使用Simapro version 8.5.2分析软件和update 852数据库进行LCA。以每年产生的325,266吨城市生活垃圾作为功能单元(Fernández-Nava et al., 2014; Beigl and Salhofer, 2004; Cherubini et al., 2009)。垃圾收集和运输、填埋、焚烧、厌氧消化材料回收、热电联产、垃圾填埋场渗滤液处理和焚烧烟气处理是考虑的生命周期阶段。图1显示了六种城市固体废物管理方案的富营养化影响潜力的LCIA结果。城市固体废物管理方案a1和A4降低了物种灭绝率,从而降低了富营养化的潜在影响,A2至A6增加了物种灭绝率。表1:过程对富营养化的贡献过程城市固体废物管理方案
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Eutrophication impact potential of solid waste management options in Harare
Six municipal solid waste management options (A1– A6) in Harare were developed and analyzed for their eutrophication impact potentials under the Life Cycle Assessment (LCA) methodology. All the options started with waste collection and transportation to a centralized waste treatment centre where a combination of various municipal solid waste management and treatment methods were considered under the different options. Results show that landfilling and material recovery for reuse and recyle are the only MSW management processes that contributes to negative eutrophication potential giving options that had landfilling (A1, A4 and A6) an overall edge. The doubling of recycling rate under A5 and increasing it to atleast 25% under A6 result in below zero eutrophication impact potentials. Results reveal that anaerobic digestion and incineration contribute to increased eutrophication potential under all the options they were considered hence need for further assessments considering other impact categories to determine the most sustainable option. water to Harare and Chitungwiza. The eutrophication of Lake Chivero is not a welcome development considering its threats to the availability of potable water for Harare and Chitungwiza. It has led to increased costs for potable water production partly contributing to the erratic potable water supplies in most parts of Harare currently being experienced. Bauman and Tillman (2004) described eutrophication as a phenomenon with the potential of affecting terrestrial and aquatic ecosystems due to nutrient enrichment namely Nitrogen (N) and phosphorus (P) in water systems. The MSW generated in Harare has an excess of biowaste constituting over 60% (UNEP, 2011) hence if improperly managed can lead to nutrient enrichment in water bodies leading to eutrophication. Magadza (2003) reported that the breakdown in hygiene has led to nutrient rich surface run-off from uncollected MSW and illegal MSW dumps significantly contributing to Lake Chivero eutrophication. The design and development of sustainable MSW management option for Harare becomes a necessity to address the human health challenges and availability of freshwater that guarantee the long term consistent supply of potable water for Harare residents. Life Cycle Assessment (LCA) has proven to be an effective tool for designing and developing sustainable and integrated MSW management as it aids the assessment of environmental loads of different MSW options (Miliute and Kazimieras Staniškis, 2010; Rives et al., 2010; Koci and Trecakova, 2011; Stucki et al., 2011; Gunamantha and Sarto, 2012; Fernández-Nava et al., 2014). Therefore, this work is an LCA based comparative study to assess the eutrophication impact potential of different MSW management options for Harare. The objective being to determine the option with the least eutrophication impact potential in light of the reported eutrophic status of the potable water sources in Harare. 2 MATERIALS AND METHODS 2.1 Description of study area The study area is Harare the capital city of Zimbabwe with an estimated population of 1,485,231 (Zimstat, 2013) and covering an area of 960.6 km 2 at an altitude of 1483 m. An estimate of 325,266 tons of MSW is generated per year (Mshandete and Parawira, 2009, Muchandiona et al., 2013, Pawandiwa, 2013, Mbiba, 2014, Hoornweg and Bhada-Tata, 2012, Emenike et al., 2013) in Harare with 60% indiscriminately collected and dumped at Pomona dumpsite the only official dumpsite whose capacity is exhausted by 2020 (Chijarira, 2013). The waste that is generated in Harare is estimated to have average composition of 42% biodegradable waste, 33% plastics, 8% metals, 14% paper and 3% glass (Nyanzou and Steven, 2014, Mudzengerere and Chigwenya, 2012). Harare sits upstream and on the catchment of its potable water source (Lake Chivero) making all the MSW management activities in Harare contributing towards the reported super eutrophic levels of the Lake. Underground water in Harare has also been reported to have been contaminated with nutrients, metals, acids and coliform bacteria (Muchandiona et al., 2013, Love et al., 2006, Eukay and Kharlamova, 2014, Kharlamova et al., 2016). 2.2 MSW management option 1 – A1 The entire 325,266 tons of MSW generated per year in Harare is indiscriminately collected before any treatment (both biodegradable and nonorganic MSW) and landfilled in a sanitary landfill with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.3 MSW management option 2 – A2 The entire 325,266 tons of MSW generated per year in Harare is indiscriminately collected before any treatment (both biodegradable and nonorganic MSW) and incinerated in an incinerator with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.4 MSW management option 3 – A3 Biodegradable MSW generated amounting to 136,612 tons is digested in an anaerobic digester producing biogas. The biogas is fed into Combined Heat and Power (CHP) generation plant to produce heat and electricity. The remaining non-biodegradable fraction 188,654 tons mixed bag MSW (107,338 tons plastics, 26,021 tons metals, 45,537 tons paper and 9,758 tons glass) is incinerated as in A2 with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.5 MSW management option 4 – A4 As in A3 difference being that the remaining non-biodegradable fraction 188,654 tons mixed bag MSW (107,338 tons plastics, 26,021 tons metals, 45,537 tons paper and 9,758 tons glass) is landfilled as in A1 with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.6 MSW management option 5 – A5 20% of the non-biodegradable MSW amounting to 37,731 tons (21,468 tons plastics, 5,204 tons metals, 9,107 tons paper and 1,952 tons glass) are recovered in the material recovery facility or sorting plant for reuse and recycling. The 80% non-biodegradable MSW remaining from the material recovery facility amounting to 150,923 tons (85,870 tons plastics, 20,817 tons metals, 36,430 tons paper and 7,806 tons glass) is incinerated as in A2 with energy recovery, flue gas treatment and treatment of leachate produced during the recovery of the incinerator bottom ash. The incinerator bottom and fly ash is used as material for road construction considering the road infrastructural needs of the country. 2.7 MSW management option 6 – A6 20% of the non-biodegradable MSW amounting to 37,731 tons (21,468 tons plastics, 5,204 tons metals, 9,107 tons paper and 1,952 tons glass) are recovered in the material recovery facility or sorting plant for reuse and recycling. The 80% non-biodegradable MSW remaining from the material recovery facility amounting to 150,923 tons (85,870 tons plastics, 20,817 tons metals, 36,430 tons paper and 7,806 tons glass) is landfilled as in A1 with biogas recovery and landfill leachate treatment. The recovered biogas is fed into Combined Heat and Power (CHP) plant to produce electricity. 2.8 Life Cycle Assessment The eutrophication impact potential for the six MSW management options was estimated using the LCA methodology with the ISO 14040 standards applied as the basis of the LCA. Simapro version 8.5.2 analyst software and update 852 database were used for the LCA under the ReCiPe 2016 v1.02 endpoint method. The yearly MSW generation of 325,266 tons was used as the functional unit (Fernández-Nava et al., 2014, Beigl and Salhofer, 2004, Cherubini et al., 2009). Waste collection and transportation, landfilling, incineration, anaerobic digestion material recovery, CHP generation, landfill leachate treatment and incineration flue gas treatment were the considered life cycle stages. 3 RESULTS AND DISCUSSIONS Figure 1 shows the LCIA results with regards to the eutrophication impact potential of the six MSW management options. MSW management options A1and A4 leads to reduced extinction rate of species thus reduced eutrophication impact potential with A2 to A6 bringing about an increased species extinction rates. Table 1: Process Contributions to eutrophication Process MSW management options
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