{"title":"低成本吸附剂去除水溶液中两种染料的平衡和热力学研究","authors":"Z. Hussain","doi":"10.22401/JNUS.21.3.03","DOIUrl":null,"url":null,"abstract":"The capability of the low cost materials viz. Dried Mint Leaves (DML) to eliminate two cationic dyes, Methylene Blue (MB) and Safranin-O (SF-O) from an aquatic solutions was studied by the technique of batch mode adsorption process. Influence of contact time, initial dye concentration (mg/L), adsorbent amount (g/L) and temperature was investigated. The equilibrium and thermodynamic peculiarities of the dyes abscession were too inspected. The empirical data were found to comply the Langmuir and Freundlich models. Also Dubinin-Radushkevich model show that the process was physisorption. The negative free energy pointed to that the adsorption processes were spontaneously feasible. The process of adsorption has been existed to be exothermic in nature. The abscession of MB was found to be more spontaneous and feasible than the removal of SF-O on the adsorbent.","PeriodicalId":255225,"journal":{"name":"Journal of Al-Nahrain University of Science","volume":"6 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Equilibrium and Thermodynamic Studies of Removal of Two Dyes from Aqueous Solutions using Low Cost Adsorbent\",\"authors\":\"Z. Hussain\",\"doi\":\"10.22401/JNUS.21.3.03\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The capability of the low cost materials viz. Dried Mint Leaves (DML) to eliminate two cationic dyes, Methylene Blue (MB) and Safranin-O (SF-O) from an aquatic solutions was studied by the technique of batch mode adsorption process. Influence of contact time, initial dye concentration (mg/L), adsorbent amount (g/L) and temperature was investigated. The equilibrium and thermodynamic peculiarities of the dyes abscession were too inspected. The empirical data were found to comply the Langmuir and Freundlich models. Also Dubinin-Radushkevich model show that the process was physisorption. The negative free energy pointed to that the adsorption processes were spontaneously feasible. The process of adsorption has been existed to be exothermic in nature. The abscession of MB was found to be more spontaneous and feasible than the removal of SF-O on the adsorbent.\",\"PeriodicalId\":255225,\"journal\":{\"name\":\"Journal of Al-Nahrain University of Science\",\"volume\":\"6 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Al-Nahrain University of Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22401/JNUS.21.3.03\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Al-Nahrain University of Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22401/JNUS.21.3.03","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
采用间歇吸附法研究了低成本原料干薄荷叶(DML)对水中亚甲基蓝(MB)和红花素- o (SF-O)两种阳离子染料的去除效果。考察了接触时间、初始染料浓度(mg/L)、吸附剂用量(g/L)和温度对吸附效果的影响。考察了染料脱落的平衡和热力学特性。实证数据符合Langmuir和Freundlich模型。Dubinin-Radushkevich模型也表明该过程为物理吸附。负自由能表明吸附过程是自发可行的。吸附过程在本质上是放热的。结果表明,在吸附剂上吸附MB比吸附SF-O更具有自发性和可行性。
Equilibrium and Thermodynamic Studies of Removal of Two Dyes from Aqueous Solutions using Low Cost Adsorbent
The capability of the low cost materials viz. Dried Mint Leaves (DML) to eliminate two cationic dyes, Methylene Blue (MB) and Safranin-O (SF-O) from an aquatic solutions was studied by the technique of batch mode adsorption process. Influence of contact time, initial dye concentration (mg/L), adsorbent amount (g/L) and temperature was investigated. The equilibrium and thermodynamic peculiarities of the dyes abscession were too inspected. The empirical data were found to comply the Langmuir and Freundlich models. Also Dubinin-Radushkevich model show that the process was physisorption. The negative free energy pointed to that the adsorption processes were spontaneously feasible. The process of adsorption has been existed to be exothermic in nature. The abscession of MB was found to be more spontaneous and feasible than the removal of SF-O on the adsorbent.