V. Suárez-Toriello, Z. Y. Méndez-Martínez, J. I. Cervantes-Arista, M. F. López-Núñez, Liliana Villafaña-López, Juan José Quiroz- Ramírez, R. Guerra-Sánchez
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引用次数: 0
摘要
在生物油和石油的精炼过程中,得到固体碳质残留物,其最终归宿是燃烧。可以通过在水介质中的氧化技术利用这些残留物,产生可溶性含氧有机化合物,类似于腐植酸物质:腐植酸、黄腐酸和腐植酸(Ashtari, et al., 2016)。腐殖质具有大量的酚基和羧基,为作物的发育提供了特性。这些包括对粘土的胶体作用、离子交换能力、金属捕获的螯合作用和对土壤微动植物群的刺激。此外,它们还可用于润滑油、吸附剂和燃料的配方中(Martinez et al., 2013)。这项工作探索了重油焦化后碳质残渣的转化,通过其在水介质中的氧化产生可溶性有机化合物,在土壤改良和其他应用中具有潜在的应用前景,从而有助于提高碳氢化合物生产链的可持续性。
Obtaining humic substances from a carbonaceous industrial residue
In the refining of bio- and petro-oils, solid carbonaceous residues are obtained whose final destination is combustion. It is possible to take advantage of these residues through the oxidation technique in an aqueous medium, producing soluble oxygenated organic compounds, analogous to humic substances: humic acids, fulvic acids and humins (Ashtari, et al., 2016). Humic substances possess a large amount of phenolic and carboxylic groups, which provide them with characteristics for crop development. These include colloidal action on clays, ion exchange capacity, chelating action for metal capture and stimulation of soil micro-fauna and -flora. Additionally, they can be used in the formulation of lubricants, adsorbents and fuels (Martinez et al., 2013). This work explores the transformation of the carbonaceous residue of heavy oil coking, through its oxidation in an aqueous medium for the production of soluble organic compounds, with potential application in soil improvement and other applications, in such a way that it contributes to increase sustainability in the hydrocarbon production chain.