粉煤灰赤泥基地聚合物的研制

M. Ambrus, G. Mucsi, R. Szabó, Balázs Kovács
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引用次数: 8

摘要

考虑到环境因素,如减少二氧化碳排放和生态足迹,利用二次原材料对可持续发展至关重要。粉煤灰是燃煤厂通过各种空气净化设备从烟气中收集的产物,赤泥是拜耳法的副产品,通过拜耳法可以从铝土矿中生产氧化铝。地聚合是一种适用于利用这些废物生产具有许多有利性能的陶瓷、水泥、混凝土等的方法。本文的主要目的是介绍由Tatabánya粉煤灰和Almásfüzitő赤泥沉积而成的地聚合物的开发和试验数据。在实验中,将赤泥加入到先前优化的粉煤灰地聚合物中,并进行了不同数量的抗压强度测试,以确定最佳的粉煤灰和赤泥比。然而,由于可以观察到试件的开裂,因此对地聚合物的耐久性进行了进一步的测试。在3、7、14、28和90天时,通过目测和FT-IR分析,研究了密封条件和RM煅烧的影响。综上所述,密封条件对粉煤灰-赤泥基地聚合物的结构特性有直接影响,但还需要进一步的实验来确定正在进行的反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The development of fly ash – red mud based geopolymer
Taking into account environmental considerations, such as decreasing CO2 emission and the ecological footprint, the utilisation of secondary raw materials is essential for sustainable development. Fly ash is the product of coal combustion plants that is collected by various air cleaning equipment from flue gas, and red mud is the by-product of the Bayer-process, through which alumina can be produced from bauxite. Geopolymerisation is a process that is suitable for the utilisation of such wastes to produce ceramics, cement, concrete etc. with many advantageous properties. The main objective of the article is to present data on the development and examination of geopolymer made out of deposited fly ash from Tatabánya and red mud from Almásfüzitő. During the experiments, red mud was added to previously optimised fly ash geopolymer in various quantities and compressive strength tests were carried out to determine the optimal fly ash and red mud ratio. However, as the cracking of the specimens could be observed, further tests were carried out on the durability of the geopolymers. The effect of the sealing conditions and RM calcination was investigated, both via visual inspection and with FT-IR analysis at the ages of 3, 7, 14, 28 and 90 days. Based on the results, it could be concluded that the sealing conditions have direct effect on the structural characteristics of fly ash – red mud based geopolymers, but further experiments should be carried out for the identification of the ongoing reactions.
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