高性能18650型NCA/石墨圆柱形电池的制备

Hafid Khusyaeri, C. Yudha, M. Rahmawati, Dewi Pratiwi, E. Dyartanti, A. Purwanto
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摘要

高能量和功率密度、长循环性能是最先进的锂离子电池的主要特点,是电动汽车储能和电源的首选之一。锂镍钴铝氧化物(NCA),即LiNi0.8Co0.15Al0.05O2,是一种具有高重量和体积能量密度的正极材料,在电力和储能领域具有广阔的应用前景。本文通过调整导电剂的组成,制备了具有高容量和优异性能的NCA/石墨电池。选择乙炔黑、炭黑和石墨KS-6作为导电添加剂。结果表明,在高电流速率下,高剂量的KS-6表现出较差的性能。相反,大量的AB循环稳定性较好,但比容量较低。最后,按KS-6与AB的混合比为2:1.5 w/w的配方,获得了高容量、高性能的电池。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fabrication of High Performance 18650-Type NCA/Graphite Cylindrical Cells
High energy and power density with long-lasting cycle performance are the main key feature of state-of-the-art Li-ion batteries, making them as one of the top choices for electric vehicle energy storage and power source. Lithium nickel cobalt aluminum oxide (NCA) specifically LiNi0.8Co0.15Al0.05O2 is cathode material with high gravimetric and volumetric energy density which is promising to be used as power and energy storage. In this paper, NCA/Graphite cells with high capacity and superior performance are fabricated via tuning of conducting agent composition. Acetylene black carbon black and graphitic KS-6 were selected as the conductive additives. Based on the result, high amount of KS-6 shows inferior performance at elevated current rate. On the contrary, high amount of AB shows better cycling stability but low specific capacity. In the end, high capacity and high-performance cells were obtained by a formula where mixture of KS-6 and AB ratio is 2:1.5 w/w.
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