高效阻蚀成分的研究、改进及耐电蚀性评价

I. E. Illarionov, Sh. V. Sadetdinov, V. Gadalov, O. Gubanov, Yuliya Skripkina
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引用次数: 0

摘要

本文介绍了硼含氮化合物的改进研究,以及基于三支溶解度等温线的H3BO3-C3H4N2-H2O体系的相变信息。通过对第二支的分析,发现了一个新的硼替咪唑化合物。给出了其性质的完整描述。此外,本文还研究了硼替咪唑和咪唑对预共析碳钢在中性介质中的腐蚀电解行为和循环强度的主要特征的影响。研究发现,在腐蚀介质中引入咪唑和硼替咪唑降低了钢的电离速率,降低了钝化状态区阳极电流密度,提高了金属循环强度的主要特性。研究表明咪唑的抑制能力低于硼替咪唑。所得的重量研究、电化学变化和腐蚀疲劳试验结果相互吻合较好,也与前人所得数据吻合较好。硼替咪唑是一种非常有效的缓蚀剂,可用于保护黑色金属及其合金。开发新型高效、环保的含硼化合物缓蚀剂是一项重要的科学技术任务。在研制新型防腐试剂的过程中,采用了现代材料科学的科学基础——物理和化学分析方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study, improvement and evaluation of electro-corrosion resistance of highly effective inhibitory compositions
The studies on the improvement of boron nitrogen-containing compounds, as well as information on phase transformations in the system H3BO3-C3H4N2-H2O, based on the solubility isotherms consisting of three branches, are presented. Based on the analysis of the second branch, a new boratimidazole compound was found. A full description of its properties is given. Furthermore, the paper presents the studies on the effect of boratimidazole and emidazole on the corrosive electrolytic behavior and the main characteristics of the cyclic strength of pre-eutectoid carbon steel in neutral media. It is found that the introduction of emidazole and boratimidazole into corrosive media reduces the ionization rate of steel, reduces the density of the anode current in the passive state region and increases the main characteristics of the cyclic strength of the metal. It has been shown that emidazole has a lower inhibitory ability than boratimidazole. The obtained experimental results of gravimetric studies, electrochemical changes and corrosion-fatigue tests are in good agreement with each other and with the previously obtained data. Boratimidazole is a quite effective corrosion inhibitor and can be used to protect ferrous metals and their alloys. The development of new effective, environmentally friendly corrosion inhibitors based on boron-containing compounds is an important scientific and technical task. To develop new compositions of anticorrosive reagents, the method of physical and chemical analysis, which is the scientific basis of modern materials science, is used in this work.
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