新型仿生闪沸注射器中scr -催化剂的使用及混合比较

P. Larsson, P. Ravenhill, L. Larsson, P. Tunestål
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引用次数: 0

摘要

柴油发动机产生的氮氧化物污染每年造成1万多人过早死亡,而且这一趋势还在增加。为了减少这一日益严重的全球性问题,必须对柴油机排气后处理系统进行改进。市场上最常见的SCR系统注入尿素水溶液,DEF在SCR催化剂的催化表面之前蒸发。由于催化剂内部的催化反应,NOx名义上转化为氮和水。目前,强力混合板和长流道加强了蒸发过程;这些,消极地,产生额外的排气背压和冷却废气降低发动机和催化剂的效率。为了达到未来排放法规的目标,必须提高SCR效率,特别是在低催化剂温度条件下,而且必须避免氨滑,因为它现在是法律所禁止的。瑞典仿生公司的新型μMist®平台技术,灵感来自庞巴迪甲壳虫,将热的,起泡的,精细雾化的,高度分散的DEF喷雾柱注入排气流。这是通过提高DEF的温度来实现的,在一个封闭的体积里,高于饱和蒸汽压力。然后迅速释放DEF,产生气泡雾化。本研究对μMist®注入器和同类领先的DEF注入器的蒸发和混合行为进行了背对背研究。试验条件是有和没有混合板和使用两种不同的流道设计。通过测量氮氧化物转化率来评估催化剂表面的喷雾分布,同时也测量催化剂后的氨滑移。本报告描述了新型μMist®注入器如何显着提高NOx转化率和催化剂表面使用率,同时显着减少氨滑。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SCR-Catalyst Utilisation and Mixing Comparison Using a Novel Biomimetic Flash-Boiling Injector
NOx pollution from Diesel engines causes over 10 000 premature deaths annually and the trend is increasing. In order to decrease this growing global problem, exhaust after-treatment systems for Diesel engines have to be improved. The most common SCR systems in the market place inject an aqueous Urea solution, DEF that evaporates prior the catalytic surface of the SCR-catalyst. Due to a catalytic reaction within the catalyst, NOx is converted nominally into Nitrogen and Water. Currently, the evaporative process is enhanced by aggressive mixer plates and long flow paths; these, negatively, create extra exhaust back pressure and cool the exhaust gases decreasing engine and catalyst efficiency. To achieve future emission legislation targets SCR efficiency has to be improved especially under low catalyst temperature conditions, plus Ammonia slip has to be avoided as it is now legislated against. Swedish Biomimetic’s novel μMist® platform technology, inspired by the Bombardier Beetle, injects a hot, effervescent, finely atomised, highly dispersed spray plume of DEF into the exhaust stream. This is achieved by raising the temperature of the DEF, in a closed volume, above its saturated vapour pressure. The DEF is then rapidly released creating effervescent atomisation. This study investigates a back to back study of the evaporating and mixing behaviour of the μMist® injector and a class leading DEF injector. The test conditions are with and without a mixer plate and the use of two different flow path designs. Spray distribution across the face of the catalyst is assessed by measuring NOx conversion whilst Ammonia slip is also measured post catalyst. This report describes how the novel μMist® injector significantly increases NOx conversion and catalyst surface usage whilst considerably reducing Ammonia slip.
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