Yingyot Poo-arpom, S. Pakapongpan, Pitirat Pholpabu, Rungtiva P. Poo-arpom
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引用次数: 1
摘要
本研究报道了一种基于循环伏安法的高选择性、稳定的氯霉素传感器。该传感器是用石墨烯-氧化铁纳米颗粒在磁丝网印刷电极(MSPE)上修饰而成的。该纳米复合材料在大表面积上具有显著的增强作用,有利于电子向电极表面转移,并具有超顺磁性。采用循环伏安法(CV)对其电化学性能进行了表征。修饰电极的电子转移速度快,表观电子转移速率常数(ks)为0.88 s−1。该传感器在0.05 ~ 0.5 mM范围内具有较宽的线性范围,CV响应速度快(3 s),信噪比为3 (s /N=3)时检测限低至17 μM,灵敏度为22.788 μA/μM。所制备的生物传感器稳定性高,重现性好。
Voltammetry based disposable sensor for antibiotic contamination in food
This research work reported a highly selective and stable chloramphenicol sensor based on cyclic voltammetry. The sensor was fabricated using graphene-iron oxide nanoparticles modified on a magnetic screen-printed electrode (MSPE). The nanocomposite has remarkable enhancement in large surface areas, facilitates electron transfer to electrode surfaces, and possesses superparamagnetism property. The electrochemical properties were characterized by cyclic voltammetry (CV). The modified electrode provided a fast electron transfer with an apparent electron transfer rate constant (ks) of 0.88 s−1. The proposed biosensor showed fast CV response (3 s) to chloramphenicol with a wide linear range from 0.05 to 0.5 mM, a low detection limit of 17 μM at a signal to noise ratio of 3 (S/N=3), and good sensitivity (22.788 μA/μM). The resulted biosensor also showed high stability and good reproducibility.