化学共沉淀法合成Pr、Cu共掺杂ZnO纳米粒子的结构和光致发光性能

Sonti Venkata Ramana, C.V. Krishna Reddy, G. Harish, C. Salma, M. Rao
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引用次数: 0

摘要

在室温下,采用低成本的化学共沉淀法将氧化锌纳米颗粒与镨(Pr)和铜(Cu)共掺杂。采用聚乙烯吡咯烷酮(PVP)作为封盖剂,在pH为9的条件下合成纳米样品。然后利用x射线衍射(XRD)、透射电子显微镜(TEM)、扫描电子显微镜(SEM)、能量色散光谱(EDS)和光致发光(PL)对合成的纳米样品进行表征。x射线衍射研究表明ZnO具有纤锌矿六方结构,未发现杂质峰。XRD研究得到的颗粒尺寸在32 ~ 46 nm之间,TEM表征的粒度也较好。SEM显微照片显示了样品的表面形貌。随着Cu掺杂浓度的增加,pr掺杂ZnO纳米样品的发光性能得到增强。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Structural and Photoluminescence Properties of Pr, Cu Co-Doped ZnO Nanoparticles Synthesized by Chemical Co-Precipitation Method
At room temperature, zinc oxide (ZnO) nanoparticles co-doped with praseodymium (Pr) and copper (Cu) using a low-cost chemical co-precipitation method. As a capping agent, polyvinylpyrrolidone (PVP) was used for synthesizing the nanosamples, and a pH of 9 was maintained. The synthesis of nanosamples was then characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and photoluminescence (PL). X-ray diffraction studies revealed the wurtzite hexagonal structure of ZnO, and no impurity peaks were found. The particle size obtained from XRD studies was 32 to 46 nm and is well supported by TEM. SEM micrographs demonstrated the surface morphology of the samples. With Cu dopant concentration, Pr-doped ZnO nanosamples exhibited enhanced luminescence properties.
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