煤变质热力学方程(CMTE)的数值计算

Mao Qinghua, Z. Xuemei, Li Dong, Hao Jingyuan
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引用次数: 0

摘要

为了定量研究煤的变质作用,通过计算反射率随时间和温度的变化以及温度随时间和反射率的变化,结果表明吴崇龙先生提出的温度-时间-反射率三元煤变质热力学方程(Cmte)是可行的。虽然只是经验公式,但数学公式比图解更方便准确,褐煤的临界温度为49.3℃,长焰煤的临界温度为56.9℃。用温度-时间反射率经验公式解释煤的变质作用。通过编制石炭系、侏罗系和白垩系中煤组温度反射(时间)图,用等温水平线或等反射竖线解释了“热时间越长,变质程度越高”的概念。文献中四川南通煤田的温度和有效变质时间进一步证明了Cmte的准确性和实用性。温度-时间反射率的数学公式不仅可以知道时间和反射率的交叉验证温度,而且可以知道与原始有效变质时间相差小于1.4%的时间。证明了温度-时间反射率经验公式可以解释煤的变质作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Numerical Evaluation of the Coal Metamorphism Thermodynamics Equation (CMTE)
In order to quantitatively study the metamorphism of coal, by calculating the changes of reflectivity with time and temperature and the changes of temperature with time and reflectivity, the results show that the temperature time reflectivity ternary coal metamorphism thermodynamic equation (Cmte) proposed by Mr. Wu Chonglong is feasible. Although it is only an empirical formula, the mathematical formula is more convenient and accurate than the diagram, The critical temperature of lignite is 49.3°C and that of long flame coal is 56.9°C. The empirical formula of temperature time reflectance is demonstrated to explain the metamorphism of coal. By compiling temperature reflection (time) maps of middle coal formation in Carboniferous, Jurassic and Cretaceous, this paper explains the concept of "the longer the thermal time, the higher the degree of metamorphism" with isothermal horizontal line or equal reflection vertical line. The temperature and effective metamorphic time in the literature of Nantong coalfield in Sichuan further prove the accuracy and practicability of Cmte. The mathematical formula of temperature time reflectance can not only know the cross verification temperature of time and reflectance, but also know the time with a difference of less than 1.4% from the original effective metamorphic time. It is proved that the empirical formula of temperature time reflectance can explain the metamorphism of coal.
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