烧结温度对Bi0.5Sb1.5Te3热电材料电输运性能的影响

Zhi-ling Bai, B. Qin
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引用次数: 0

摘要

采用真空固相反应烧结法成功制备了Bi0.5Sb1.5Te3热电材料。研究了不同烧结温度对Bi0.5Sb1.5Te3热电材料电输运性能的影响。结果表明:随着烧结温度的升高,Bi0.5Sb1.5Te3复合材料的Seebeck系数先增大后减小;Bi0.5Sb1.5Te3复合材料的电阻率随烧结温度的升高呈波形变化。当烧结温度为823K时,Bio.5Sb1.5Te3化合物的电阻率达到最小值。随着烧结温度的升高,Bi0.5Sb1.5Te3化合物的PF值先增大后减小。Bi0.5Sb1.5Te3化合物的PF值在烧结温度为823K时达到最大值。在723K、773K、823K、873K和923K 5种烧结温度条件下,823K制备的Bio.5Sb1.5Te3化合物具有最佳的电输运性能。烧结温度为823K时,Bio.5Sb1.5Te3化合物的Seebeck系数为231.893μV-K-1,电阻率为3.28mΩ•cm, PF值为1639.46pW•m-1•K-2。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Sintering Temperature on Electrical Transport Properties of Bi0.5Sb1.5Te3 Thermoelectric Materials
Bi0.5Sb1.5Te3 thermoelectric materials were successfully obtained by vacuum solid-state reaction sintering method. The effects of different sintering temperatures on the electrical transport properties of Bi0.5Sb1.5Te3 thermoelectric materials were investigated. The results show that the Seebeck coefficient of Bi0.5Sb1.5Te3 compound increases first and then decreases with the increase of sintering temperature. The resistivity of Bi0.5Sb1.5Te3 compound changes in wave shape with the increasing sintering temperature. The resistivity of Bio.5Sb1.5Te3 compound reaches the minimum value when the sintering temperature is 823K. With the increasing sintering temperature, the PF value of Bi0.5Sb1.5Te3 compound increases first and then decreases. The PF value of Bi0.5Sb1.5Te3 compound reaches the maximum value when the sintering temperature is 823K. Under five sintering temperature conditions of 723K, 773K, 823K, 873K, and 923K, the Bio.5Sb1.5Te3 compound prepared at 823K has the best electrical transport performance. When the sintering temperature is 823K, the Seebeck coefficient, resistivity and PF value of Bio.5Sb1.5Te3 compound are 231.893μV-K-1, 3.28mΩ•cm, 1639.46pW•m-1•K-2, respectively.
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