V. Drozdov, A. B. Arbuzov, M. Trenikhin, N. N. Leont’eva, I. V. Muromtsev, A. Babenko, R. R. Izmailov, A. Lavrenov
{"title":"活化Al-M (M = Fe, Co, Ni)合金:形成、结构特征及其在催化氯金属Al(M)/Cl配合物合成低温转化烃类中的应用","authors":"V. Drozdov, A. B. Arbuzov, M. Trenikhin, N. N. Leont’eva, I. V. Muromtsev, A. Babenko, R. R. Izmailov, A. Lavrenov","doi":"10.1063/1.5122906","DOIUrl":null,"url":null,"abstract":"Some Al / M alloys (M = Fe, Co, Ni, Cu) with different element ratios and phase composition were activated with a liquid Ga / In eutectic at 150 ° C in a vacuum glass reactor for about 2 hours. This method of activation of binary aluminum alloys is very important in catalysis due to the increased reactivity of aluminum and these alloys with respect to chlorine-containing compounds. The corresponding interactions lead to the formation of metal-aluminum chloride complexes, which are active in many practically important low-temperature reactions of hydrocarbons.Some Al / M alloys (M = Fe, Co, Ni, Cu) with different element ratios and phase composition were activated with a liquid Ga / In eutectic at 150 ° C in a vacuum glass reactor for about 2 hours. This method of activation of binary aluminum alloys is very important in catalysis due to the increased reactivity of aluminum and these alloys with respect to chlorine-containing compounds. The corresponding interactions lead to the formation of metal-aluminum chloride complexes, which are active in many practically important low-temperature reactions of hydrocarbons.","PeriodicalId":177536,"journal":{"name":"21ST CENTURY: CHEMISTRY TO LIFE","volume":"6 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2019-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Activated Al-M (M = Fe, Co, Ni) alloys: Features of formation, structure and use in the catalytic metal chloride Al(M)/Cl complexes synthesis for low-temperature conversion of hydrocarbons\",\"authors\":\"V. Drozdov, A. B. Arbuzov, M. Trenikhin, N. N. Leont’eva, I. V. Muromtsev, A. Babenko, R. R. Izmailov, A. Lavrenov\",\"doi\":\"10.1063/1.5122906\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Some Al / M alloys (M = Fe, Co, Ni, Cu) with different element ratios and phase composition were activated with a liquid Ga / In eutectic at 150 ° C in a vacuum glass reactor for about 2 hours. This method of activation of binary aluminum alloys is very important in catalysis due to the increased reactivity of aluminum and these alloys with respect to chlorine-containing compounds. The corresponding interactions lead to the formation of metal-aluminum chloride complexes, which are active in many practically important low-temperature reactions of hydrocarbons.Some Al / M alloys (M = Fe, Co, Ni, Cu) with different element ratios and phase composition were activated with a liquid Ga / In eutectic at 150 ° C in a vacuum glass reactor for about 2 hours. This method of activation of binary aluminum alloys is very important in catalysis due to the increased reactivity of aluminum and these alloys with respect to chlorine-containing compounds. The corresponding interactions lead to the formation of metal-aluminum chloride complexes, which are active in many practically important low-temperature reactions of hydrocarbons.\",\"PeriodicalId\":177536,\"journal\":{\"name\":\"21ST CENTURY: CHEMISTRY TO LIFE\",\"volume\":\"6 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-08-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"21ST CENTURY: CHEMISTRY TO LIFE\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1063/1.5122906\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"21ST CENTURY: CHEMISTRY TO LIFE","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/1.5122906","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Activated Al-M (M = Fe, Co, Ni) alloys: Features of formation, structure and use in the catalytic metal chloride Al(M)/Cl complexes synthesis for low-temperature conversion of hydrocarbons
Some Al / M alloys (M = Fe, Co, Ni, Cu) with different element ratios and phase composition were activated with a liquid Ga / In eutectic at 150 ° C in a vacuum glass reactor for about 2 hours. This method of activation of binary aluminum alloys is very important in catalysis due to the increased reactivity of aluminum and these alloys with respect to chlorine-containing compounds. The corresponding interactions lead to the formation of metal-aluminum chloride complexes, which are active in many practically important low-temperature reactions of hydrocarbons.Some Al / M alloys (M = Fe, Co, Ni, Cu) with different element ratios and phase composition were activated with a liquid Ga / In eutectic at 150 ° C in a vacuum glass reactor for about 2 hours. This method of activation of binary aluminum alloys is very important in catalysis due to the increased reactivity of aluminum and these alloys with respect to chlorine-containing compounds. The corresponding interactions lead to the formation of metal-aluminum chloride complexes, which are active in many practically important low-temperature reactions of hydrocarbons.