高含硫气田开发面临的挑战与上游非金属矿的机遇

Khaled H. Almuhammadi, Anwar Md. Parvez, Mustafa Buali, O. D. Salazar Vidal, A. Bukhamseen
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摘要

超过10% H2S浓度的高酸性油田被认为是上游环境中需要合适的管状部件和附件以确保可持续生产的恶劣环境之一。这种作业环境具有挑战性,由于在较高的分压和高温(HPHT)下H2S浓度较高,因此耐久性和安全性是最重要的问题。对于H2S浓度高于10%的井(即高H2S井)和H2S浓度超过25%的井(通常被称为超高H2S井),风险会放大。在井下,高温下的高硫化氢会加剧气体作业中的腐蚀,给井下作业带来额外的挑战。选择合适的材料以保证井况的可持续发展是高温高压气井开发的重要因素之一。研究人员确定了各种挑战,包括选择能够承受短期和长期H2S和CO2分压的经济高效材料,以及控制普遍的CO2腐蚀、硫化物应力开裂(SSC)和应力导向氢致开裂(SOHIC)。随着非金属材料(NM)在油气行业多个应用领域的进步,它有望为高温高压井下应用提供替代CRA合金材料的替代材料解决方案。纳米材料重量轻,除了在高H2S环境中具有出色的耐腐蚀性外,还可以承受更高的强度。此外,由于其高设计灵活性和耐用性,它们可以被设计成满足预期的应用。在井下应用中,有许多纳米技术产品已经应用于酸性环境中,包括密封胶、井下附件和工具,纳米技术的应用范围也在不断扩大。本文重点介绍了连续管、压力控制设备和弹性体等纳米产品在高酸油田的应用概念,以及这些关键部件的开发和部署所面临的挑战。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Challenges in High Sour Gas Field Development and Non-Metallics Opportunities in Upstream Processes
High sour fields beyond 10% H2S concentration are considered one of the severe environments that require suitable tubular components and accessories in upstream environment to ensure sustainable production. Such environments represent a challenging operating envelop where durability and safety are the top concerns due to higher H2S concentration at a higher partial pressure and higher temperature (HPHT). The risk is amplified for the wells with higher than 10% H2S concentration, namely the High H2S wells, and those exceeding 25% H2S concentration which are typically labeled as Ultra-High H2S wells. Corrosion in gas operations can be aggravated in downhole where high H2S at higher temperatures pose additional challenges. Selection of proper material to ensure a sustainable well condition is one of the important elements for the development of these HPHT gas wells. Various challenges were identified, including the selection of cost-effective material which is capable of withstanding short and long term H2S and CO2 partial pressures as well as control generalized CO2 corrosion, sulfide stress cracking (SSC), and stress-oriented hydrogen induced cracking (SOHIC). With the advancement of Non-Metallics (NM) materials in several applications across the O&G sector, it holds a promise to provide an alternative material solution in lieu of CRA alloy material for the HPHT downhole applications. NM materials are lightweight and they can be designed to withstand higher strength capability in addition to their outstanding corrosion resistance properties in a high H2S environment. Moreover, they can be engineered to fulfill the intended application due to their high design flexibility and durability. In the downhole applications, there is a number of NM products that have been implemented in sour environments, including sealants as well as downhole accessories and tools, where the list of NM technologies is considerably growing. This paper highlights the concept of using NM products such as coiled tubulars, pressure control equipment and elastomers as well as the challenges on the development and deployment of these key components in high sour fields.
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