{"title":"ISRU完整的储氢系统","authors":"P. Schubert","doi":"10.2514/6.2018-5367","DOIUrl":null,"url":null,"abstract":"New technologies make it possible to build in space a complete hydrogen storage system using ISRU methods and techniques. Hydrogen can be stored in a solid-state form on the surface atoms of high surface area matrices such as those of porous silicon. Silicon is abundant in regolith and can be purified using a purely mechanical means which results in particulates in the scale range of tens of nanometers. Reagents used to porosify these nano-particles can be regenerated thermally to essentially eliminate the need for resupply from earth. Catalysts are needed to divide dihydrogen gas into atomic hydrogen for solid-state adsorption and to mediate the temperatures and pressures of charge and discharge into ranges easily achievable with simple equipment. Recent research has identified the utility of non-platinum group catalyst materials which are widespread on the moon. Rapid discharge, needed for propulsion, is possible with infra-red illumination at wavelengths which pass through pure silicon but are absorbed by the silicon-hydrogen bond. Such IR emitters can be fabricated by embossing of silica and additive manufacturing of metals. Control and power electronics can be fabricated using a patented process designed for space operations, and built on either silicon or silicon carbide substrates derived from regolith. Bringing these five technologies together for the first time allows a system which can be fed with moderate pressure gaseous hydrogen at moderate temperatures, stored for long durations with minimum loss, then released upon demand across a wide range of controllable rates. Such a system can displace the need for cryogenic hydrogen storage. Being suitable to bottom-up fabrication using only in-space materials makes this a “green” ISRU technology to store hydrogen for fuel cells, rocket engines, and chemical processes.","PeriodicalId":366106,"journal":{"name":"2018 AIAA SPACE and Astronautics Forum and Exposition","volume":"34 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2018-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Complete Hydrogen Storage System by ISRU\",\"authors\":\"P. Schubert\",\"doi\":\"10.2514/6.2018-5367\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"New technologies make it possible to build in space a complete hydrogen storage system using ISRU methods and techniques. Hydrogen can be stored in a solid-state form on the surface atoms of high surface area matrices such as those of porous silicon. Silicon is abundant in regolith and can be purified using a purely mechanical means which results in particulates in the scale range of tens of nanometers. Reagents used to porosify these nano-particles can be regenerated thermally to essentially eliminate the need for resupply from earth. Catalysts are needed to divide dihydrogen gas into atomic hydrogen for solid-state adsorption and to mediate the temperatures and pressures of charge and discharge into ranges easily achievable with simple equipment. Recent research has identified the utility of non-platinum group catalyst materials which are widespread on the moon. Rapid discharge, needed for propulsion, is possible with infra-red illumination at wavelengths which pass through pure silicon but are absorbed by the silicon-hydrogen bond. Such IR emitters can be fabricated by embossing of silica and additive manufacturing of metals. Control and power electronics can be fabricated using a patented process designed for space operations, and built on either silicon or silicon carbide substrates derived from regolith. Bringing these five technologies together for the first time allows a system which can be fed with moderate pressure gaseous hydrogen at moderate temperatures, stored for long durations with minimum loss, then released upon demand across a wide range of controllable rates. Such a system can displace the need for cryogenic hydrogen storage. Being suitable to bottom-up fabrication using only in-space materials makes this a “green” ISRU technology to store hydrogen for fuel cells, rocket engines, and chemical processes.\",\"PeriodicalId\":366106,\"journal\":{\"name\":\"2018 AIAA SPACE and Astronautics Forum and Exposition\",\"volume\":\"34 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-09-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2018 AIAA SPACE and Astronautics Forum and Exposition\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2514/6.2018-5367\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2018 AIAA SPACE and Astronautics Forum and Exposition","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2514/6.2018-5367","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
New technologies make it possible to build in space a complete hydrogen storage system using ISRU methods and techniques. Hydrogen can be stored in a solid-state form on the surface atoms of high surface area matrices such as those of porous silicon. Silicon is abundant in regolith and can be purified using a purely mechanical means which results in particulates in the scale range of tens of nanometers. Reagents used to porosify these nano-particles can be regenerated thermally to essentially eliminate the need for resupply from earth. Catalysts are needed to divide dihydrogen gas into atomic hydrogen for solid-state adsorption and to mediate the temperatures and pressures of charge and discharge into ranges easily achievable with simple equipment. Recent research has identified the utility of non-platinum group catalyst materials which are widespread on the moon. Rapid discharge, needed for propulsion, is possible with infra-red illumination at wavelengths which pass through pure silicon but are absorbed by the silicon-hydrogen bond. Such IR emitters can be fabricated by embossing of silica and additive manufacturing of metals. Control and power electronics can be fabricated using a patented process designed for space operations, and built on either silicon or silicon carbide substrates derived from regolith. Bringing these five technologies together for the first time allows a system which can be fed with moderate pressure gaseous hydrogen at moderate temperatures, stored for long durations with minimum loss, then released upon demand across a wide range of controllable rates. Such a system can displace the need for cryogenic hydrogen storage. Being suitable to bottom-up fabrication using only in-space materials makes this a “green” ISRU technology to store hydrogen for fuel cells, rocket engines, and chemical processes.