多态性与超分子异构体:配位聚合物的僵局

Francisco Sánchez-Férez, J. Pons
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引用次数: 1

摘要

接下来的章节,概述了化学和晶体学之间的狭窄联系,这推动了多态性的识别,并为理解结构-性质关系提供了宝贵的基础。它最初是为有机物质设想的,但实际上被金属有机产物所接受,特别是在配位聚合物的研究中。所有的技术进步都为晶体结构形成的控制提供了深刻的见解,揭示了任何施加在物质上的刺激都可以发生结构转变。这导致在工业和学术领域实施了几种方法,揭示了迄今为止尚未得到很好理解的结果的来源。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polymorphism and Supramolecular Isomerism: The Impasse of Coordination Polymers
The chapter presented hereafter, outlines the narrow link between chemistry and crystallography that impelled the identification of polymorphism and provided a priceless grounding to understand structure-properties relationship. It was initially conceived for organic substances but actually embraced by metal–organic products, especially in the study of coordination polymers. All of the technologic advances have provided profound insights on the control of crystal structures formation revealing that any applied stimulus over a substance can undergo a structural transformation. This has led to the implementation of several methodologies in the industrial and academic segment shedding light on the source of hitherto, not well understood results.
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