气体燃料中氢的富集对分布燃烧的影响

Serhat Karyeyen, Joseph S. Feser, A. Gupta
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摘要

高强度无色分布燃烧是一种很有前途的燃烧技术,因为它可以大大减少NO和CO等污染物的排放,以及更高的热均匀性、火焰稳定性和燃烧效率。实现分布条件的主要要求是在点火前提供可控的反应热产物气体夹带到新鲜混合物中。这样,氧浓度降低,反应速率降低,混合时间延长,反应区体积分布增大。尽管分布式燃烧已经被广泛地研究了各种热负荷和强度、燃料、几何形状,但与燃料灵活性相关的信息有限。因此,研究富氢气体燃料对于更好地理解分布式燃烧系统中的低热量高火焰速度燃料具有重要意义。本研究通过使用N2或CO2作为稀释剂,在旋流稳定燃烧器中研究了三种不同含氢气体燃料(体积40-60%),以达到分布条件。在火焰前获得了OH*化学发光火焰特征,并从燃烧室出口测量了排放量。结果表明,氢浓度和稀释剂类型对氧浓度均有显著影响,并在此条件下向CDC过渡。对于各种气体燃料,在含氧浓度为10-12%(含N2)和13-15%(含CO2)的情况下,得到了分布条件。结果表明,由于氢的燃烧速度较快,高含氢燃料在较低的氧浓度下发生向CDC的过渡。火焰图像表明,在良好的CDC条件下,消除了气体燃料的闪回倾向,提高了火焰稳定性。对于NO污染物排放,在CDC条件下达到了超低水平(小于1 ppm),而CO污染物排放随着条件接近分布条件逐渐下降,然后由于较低的可燃性极限和CO2的解离而略有增加。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Hydrogen Enrichment Effects in Gaseous Fuels on Distributed Combustion
High intensity colorless distributed combustion has been a promising combustion technique as it enables much reduced pollutant emissions such as NO and CO, as well as more thermal uniformity, flame stability and combustion efficiency. The main requirement for achieving distributed conditions is to provide controlled entrainment of reactive hot product gases into the fresh mixture prior to ignition. In this way, the oxygen concentration is reduced, which results in lower reaction rates, promoting longer mixing times and volumetric distribution of the reaction zones. Though distributed combustion has been extensively studied for various heat loads and intensities, fuels, geometries, there is limited information related to fuel flexibility. Therefore, it is of interest to investigate hydrogen enriched gaseous fuels for greater understanding of low calorific high flame speed fuels in a distributed combustion system. Three various hydrogen content gaseous fuel (40–60% by volume) were investigated in a swirl-stabilized burner for this study, through the use of either N2 or CO2 as the diluent in order to achieve distributed conditions. The OH* chemiluminescence flame signatures were obtained in the flame front and emissions were measured from the combustor exit. The results showed that both the hydrogen concentration and diluent type considerably impacted the oxygen concentration at which transition to CDC occurred. Distributed conditions were achieved at oxygen concentrations of 10–12% with entrained N2 and 13–15% with entrained CO2 for various gaseous fuels consumed. It was determined that the transition to CDC occurred at a lower oxygen concentration for high hydrogen content fuels due to the higher flame speed of hydrogen. The flame images demonstrated that the flashback propensity of the gaseous fuels were eliminated and enhanced flame stability was achieved under the favorable CDC conditions. For NO pollutant emission, ultra-low NO level was achieved under CDC (less than 1 ppm) while CO pollutant emission decreased gradually with condition approaching distributed conditions, and then increased slightly due to the lower flammability limit and dissociation of CO2.
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