新型太阳能储能材料——微胶囊化石蜡的制备与评价

M. Hawlader, M. S. Uddin, H. Zhu
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引用次数: 88

摘要

采用复凝聚法制备了微囊化石蜡这种新型太阳能储能材料,并从包封率、亲水性、储能容量和尺寸分布等方面对其性能进行了评价。基于表面响应法设计试验,优化加工工艺条件。微胶囊化石蜡颗粒尺寸为50 ~ 100 μm。当乳化时间为10min,甲醛(HCHO)加入量为6 ~ 8 ml (2.9 ~ 3.8% w/w)时,石蜡与涂层(菜单)的比例不同,石蜡包封率较高。研究还发现,涂层与石蜡比越高,石蜡包封率越高。微囊化石蜡的亲水性主要取决于石蜡与涂层的比例。比值越大,产物亲水性越低。在相同石蜡与涂料配比下,HCHO浓度越高,产物亲水性越低。随着石蜡与涂层的比例不同,微胶囊化石蜡在相变过程中表现出较大的储放能(20 ~ 90 J/g)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
PREPARATION AND EVALUATION OF A NOVEL SOLAR STORAGE MATERIAL: MICROENCAPSULATED PARAFFIN
Microencapsulated paraffin, a novel solar storage material, was prepared by complex coacervation technique and its performance was evaluated in terms 1of encapsulation ratio, hydrophilicity, energy storage capacity, and size distribution. The experiments were designed, based on surface response method, to optimise the processing conditions. The sizes of the microencapsulated paraffin particle were 50–100 μm. For an emulsification time of l0min and the addition of 6–8 ml (2.9−3.8% w/w) of formaldehyde (HCHO), the paraffin encapsulation ratio was found higher in different ratio of paraffin wax to coating (menu). It was also found that a higher coating to paraffin ratio leads to a higher paraffin encapsulation ratio. The hydrophilicity value of microencapsulated paraffin depended mainly on the ratio of paraffin to coating. The higher the ratio, the lower was its product hydrophilicity. In the same ratio of paraffin wax to coating, the higher concentration of HCHO led to a lower hydrophilicity of the product. The microencapsulated paraffin has shown large energy storage and release capacity (20–90 J/g) during its phase change depending on different ratios of paraffin wax to coating.
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