E. Taer, Nazilah Nikmatun, Apriwandi, Agustino, R. Taslim, Ezri Hidayat
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引用次数: 0
摘要
活性炭粉末由于其优异的物理和电化学性能,是一种广泛应用于大规模应用的电极材料,特别是超级电容器。采用单步热解和NaOH溶液化学活化法制备了椰壳自粘炭粉。在N2/CO2气氛中进行了一步热解,包括炭化和物理活化。750°C、800°C、850°C和900°C的物理温度是评价自粘活性炭性能的主要焦点。电极的密度和微晶特性受物理活化温度的影响。基于质量、直径、厚度等自粘减碳尺寸的方法,对密度特征进行了评价。用x射线衍射法对活性炭的微晶行为进行了表征,表明活性炭具有良好的非晶性。在对称型超级电容器电池中对自粘式活性炭电极进行了表征和评价。利用循环伏安法对碳电极进行电化学表征,发现在1 M H2SO4电解液中,在1 mV的低扫描速率下,碳电极具有96 fg -1的高比电容。s-1,能量比和功率比为13.33 Wh。kg-1和48.03 W.kg-1。
The Self-Adhesive Carbon Powder Based on Coconut Coir Fiber as Supercapacitor Application
Activated carbon powder is a popular material used as an electrode material for large scale applications, especially supercapacitors because of its excellent physical and electrochemical properties. Self-adhesive carbon powder based on coconut coir was prepared via single-step pyrolysis and chemical activation with NaOH solution. A single-step pyrolysis was performed, including carbonization and physical activation in the N2/CO2 atmosphere. The physical temperature of 750 °C, 800 °C, 850 °C and 900 °C is the major focus to evaluate the behavior of self-adhesive activated carbon. The density and the microcrystalline characteristics of the electrodes are influenced by the physical activation temperature. The density feature was evaluated based on the approach of self-adhesive carbon reduction dimensions such as mass, diameter, and thickness. Microcrystalline behavior was performed by using X-ray diffraction method, and it has shown the good amorphous properties of the activated carbon. The self-adhesive activated carbon electrodes were characterized and evaluated in symmetrical supercapacitor cells. The electrochemical characterization of the carbon electrodes using cyclic voltammetry method found that the high specific capacitance of 96 F.g-1 in 1 M H2SO4 electrolyte at a low scan rate of 1 mV.s-1 with energy specific and power specific of 13.33 Wh.kg-1 and 48.03 W.kg-1, respectively.