固定床反应器在太阳辐射下降解除草剂的性能

N. Chekir, D. Tassalit, M. Mellal, O. Benhabiles, N. Sahraoui
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引用次数: 1

摘要

光催化最有可能取代活性炭吸附、化学氧化、生物处理等传统的废水处理技术。光催化是一种催化剂,半导体是二氧化钛,二氧化钛与紫外线光源作为太阳的结合。它还具有在待处理的介质中不引入添加剂的优点。然而,当纳米颗粒以浆料形式应用时,由于阻碍效应,纳米颗粒的团聚会导致光催化性能严重下降。此外,本研究还为光催化降解处理农药污染水的催化剂固定化提供了载体。本文研究了两种二氧化钛(商业介质Ahlstrom和浸渍在玻璃上的二氧化钛)在固定床反应器中作为光催化载体在太阳辐射下降解美曲津除草剂的性能。在不同的底物条件和pH溶液条件下研究了其降解性能。在工业载体1048上固定化TiO2, 180 min的太阳光催化降解率可达100%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fixed Bed Reactor Performance for Herbicide Degradation Under Solar Radiation
Photocatalysis has the best potential to replace the traditional wastewater treatment techniques such as activated carbon adsorption, chemical oxidation, and biological treatment. Photocatalysis is a combination of a catalyst semiconductor is titanium dioxide TiO2 with an ultraviolet light source as the sun. It has the added advantage of not introducing additives in the medium to be treated. However, when applied in slurry form, agglomeration of nanoparticle will lead to serious decrease in photocatalytic performance due to hinderance effect. Further, the present study has made an effort to use a support for the immobilization of catalyst for treating the pesticide polluted water by photocatalytic degradation. In the present paper, we present the performance of 2 kinds of Titanium dioxide (Commercial Media Ahlstrom and impregned TiO2 on glass) as photocatlytic support in fixed bed reactor for the degradation of Metribuzin herbicide under solar radiation. The degradation Performance was studied under various conditions such as substrate and pH solution. Solar photocatalytic degradation rate can reach 100% during 180 min of treatment with using TiO2 immobilized on commercial support media 1048.
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