利用农业废弃物改性处理尼日尔三角洲油田采出水

Okereke
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引用次数: 0

摘要

油气储层的组成成分之一是采出水。采出水大多数时候含有有毒物质和其他杂质,影响生态系统。大多数现有的处理技术都不能很有效地将一些污染物减少到可接受的处置限度。香蕉皮用清水洗净,太阳晒干3天,在105±50℃下烘干3小时。将其研磨,筛选(150和300微米),然后用0.4mol/L的HNO3处理,用清水冲洗以去除任何可能干扰结果的色素。样品(采出水)使用150微米尺寸的吸附剂在吸附室中处理4小时。300微米尺寸重复处理。对处理后的样品进行了分析和表征。在150微米尺寸下,金属(Pb、Ni、Cd、Cu、Fe、Mg、Cr、Zn、Mn、Ca、Ar、B、Sn、Ba)的浓度降低率分别为87.18%、23.08%、42.86%、100%、80.12%、34.33%、28.93%、45.40%、47.89%、97.18%、33.06%、43.24%、62.50%和44.44%。同样尺寸为300微米的金属也得到了类似的还原。吸附剂越细,吸附剂效果越好。Langmuir模型最能描述铅的吸附,等温线R2为0.98,Freundlich模型最能描述镍和铁的吸附,等温线R2分别为0.85和0.93。采用150微米尺寸的香蕉皮对尼日尔三角洲油田采出水中的污染物进行了有效处理,效果最好。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Management of Produced Water from Niger Delta Oilfield with Modified Agricultural Waste
Hydrocarbon reservoirs contain produced water as one of its constituents. Produced water most times contains toxic materials and other impurities that affect the ecosystem. Most of the available treatment techniques have not been very effective in reducing some of the contaminants to an acceptable disposal limits.Banana peels was washed with clean water, dried under the sun for three days, and oven-dried at 105±5o C for 3 hours. It was milled, sieved (150 and 300 microns,), and then treated with 0.4mol/L HNO3 , rinsed with clean water to remove any pigment that might interfere with the result. Sample (produced water) was treated in adsorption chamber for 4 hours using 150 micron size of adsorbent. Treatment was repeated with 300 micron size. Treated sample was analyzed and characterized. For the 150 micron size, the percentage reductions for the metals concentration (Pb, Ni, Cd, Cu, Fe, Mg, Cr, Zn, Mn, Ca, Ar, B, Sn, Ba) were found to be 87.18%, 23.08%, 42.86%, 100%, 80.12%, 34.33%, 28.93%, 45.40%, 47.89%, 97.18%, 33.06%, 43.24%, 62.50%, and 44.44% respectively. Similar reductions in same metals with 300 micron size were equally obtained. The finer adsorbent was more effective. Langmuir model best described the adsorption of lead with isotherm R2 of 0.98, while Freundlich described the adsorption of nickel and iron, with isotherms R2 of 0.85 and 0.93 respectively. Produced water from Niger Delta oil field was effectively treated of contaminants using banana peels with 150 micron size produced the best result.
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