低密度聚乙烯/纳米zno复合材料击穿性能研究

Yujia Cheng, N. Guo, Ru Wang, Xiaohong Zhang
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引用次数: 4

摘要

近十年来,纳米复合材料的介电性能引起了人们的广泛关注。本文采用硅烷偶联剂KH-570和钛酸酯偶联剂105、101、TC-F作为改性剂。将KH-570或TC-F等改性过的纳米氧化锌加入到低密度聚乙烯中。最后,研究了复合材料的电击穿性能。测试结果表明,当纳米zno含量为3%时,复合材料的击穿场强比原LDPE高11%。ZnO颗粒越小,相同含量的纳米复合材料击穿强度越高。硅烷偶联剂(KH-570)处理的纳米zno复合材料的击穿强度高于钛酸盐偶联剂处理的纳米zno复合材料。红外光谱分析发现,纳米氧化锌与聚乙烯大分子链的结合得到了有效改善。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation on breakdown properties of low-density polyethylene / nano-ZnO composites
The dielectric properties of Nano-composites has attract tremendous attention during the past decade. In present paper, the silane coupling agent (KH-570) and titanate coupling agent (105, 101, TC-F) is used as modifiers. The nanometer zinc oxide which has been modified by KH-570 or TC-F etc is added to the low density polyethylene. In the end, the electrical breakdown properties of the composites are investigated. The test results show that when the content of nano-ZnO was 3%, breakdown field strength of the composites is higher than origin LDPE 11%. The smaller ZnO particles in size, the higher breakdown strength of the nano-composite with the same content of nano-ZnO is. The breakdown strength of nano-composites with nano-ZnO which is treated by silane coupling agent (KH-570) is higher than those with nano-ZnO treated by titanate coupling agent. It can be found that combination of nanometer zinc oxide and polyethylene macromolecular chain is effectively improved by infrared spectrum.
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