Distinction between Natural and Anthropogenic Contaminants of Atmospheric Precipitates from Northeastern Kansas Based on Their Elemental Contents and Strontium Isotopic Signatures

This study was designed to identify and possibly evaluate the changing occurrence of major pollutants in different atmospheric precipitates (rain, snow and hail) that were collected in northeastern Kansas next to the Konza Prairie Preservation site by analyzing their elemental and Sr isotope compositions. Potential pollutants like the local soils and their clay material, as well as the fly ash of a nearby coal-burning power plant were also analyzed. Positively correlated with K in the analyzed precipitates, the Na contents of the precipitates suggest a supply of fertilizers and/or natural plant organics. Combining the four identified pollutants of the precipitates that is to say the soils, the fly ash, the fertilizers and the plants allows evaluation of their changing contribution during a single precipitation event. The duration of the rain events monitors also the changing contribution of the identified pollutants. Variations of the 87Sr/86Sr ratio from precipitates during lasting events are confirmed by changing distribution patterns of the REEs. In fact, soil minerals contribute mostly at the beginning of the precipitation events and are replaced progressively by the industrial fly ash that becomes dominant towards the end of the precipitation events, depending on the duration and wind directions. At last not least, the different contaminants are recognizable by changing elemental contributions, REE distribution patterns and 87Sr/86Sr ratios. Their variable occurrence can be followed in the wet solutes, but a strict quantification cannot be provided due to elemental and isotopic interconnections between the natural and the anthropogenic contributors.