{"title":"端部生长:用于合成嵌段共聚物的聚合物端基的反应性","authors":"José E. Báez","doi":"10.1016/j.eq.2015.11.001","DOIUrl":null,"url":null,"abstract":"<div><p>Three different cases of reactions using end-groups in polymers were analyzed for the synthesis of block copolymers, such as: a) azide (R<img>N<sub>3</sub>) and alkine (R<img>C<img>CH) end groups to obtain a 1,3-dipolar cycloaddition (click chemistry), b) α,ω-hydroxy telechelic polymers (HO<img>R<img>OH) and diisocyanates (OCN<img>R<img>NCO) to synthesize polyurethanes by polycondesation and c) alkyl halides (R<img>Cl or R<img>Br) to prepare block copolymers derived of polystyrene by atom transfer radical polymerization (ATRP).</p></div>","PeriodicalId":39011,"journal":{"name":"Educacion Quimica","volume":"27 2","pages":"Pages 97-104"},"PeriodicalIF":0.0000,"publicationDate":"2016-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.eq.2015.11.001","citationCount":"2","resultStr":"{\"title\":\"El crecimiento en los extremos: reactividad de grupos terminales en polímeros para la síntesis de copolímeros bloque\",\"authors\":\"José E. Báez\",\"doi\":\"10.1016/j.eq.2015.11.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Three different cases of reactions using end-groups in polymers were analyzed for the synthesis of block copolymers, such as: a) azide (R<img>N<sub>3</sub>) and alkine (R<img>C<img>CH) end groups to obtain a 1,3-dipolar cycloaddition (click chemistry), b) α,ω-hydroxy telechelic polymers (HO<img>R<img>OH) and diisocyanates (OCN<img>R<img>NCO) to synthesize polyurethanes by polycondesation and c) alkyl halides (R<img>Cl or R<img>Br) to prepare block copolymers derived of polystyrene by atom transfer radical polymerization (ATRP).</p></div>\",\"PeriodicalId\":39011,\"journal\":{\"name\":\"Educacion Quimica\",\"volume\":\"27 2\",\"pages\":\"Pages 97-104\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.eq.2015.11.001\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Educacion Quimica\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0187893X15000919\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Social Sciences\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Educacion Quimica","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0187893X15000919","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Social Sciences","Score":null,"Total":0}
El crecimiento en los extremos: reactividad de grupos terminales en polímeros para la síntesis de copolímeros bloque
Three different cases of reactions using end-groups in polymers were analyzed for the synthesis of block copolymers, such as: a) azide (RN3) and alkine (RCCH) end groups to obtain a 1,3-dipolar cycloaddition (click chemistry), b) α,ω-hydroxy telechelic polymers (HOROH) and diisocyanates (OCNRNCO) to synthesize polyurethanes by polycondesation and c) alkyl halides (RCl or RBr) to prepare block copolymers derived of polystyrene by atom transfer radical polymerization (ATRP).
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