红外传感器用氧化氮化铟锡薄膜的电学特性

M. Sparvoli, Victor Pederzini, L. R. Damiani, Peter Lubomir Polak, I. Abe, A. Lopes, I. Pereyra, R. Onmori
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摘要

透明导电氧化物(TCOs)是一类具有宽禁带($\sim3.1$ eV)的材料。这些材料具有良好的透明度和导电性。氧化铟锡(ITO)是一种高带隙的简并半导体材料,在太阳光谱可见范围内透明,属于TCO类。当氮加入到ITO薄膜中,它就形成了一种新的半导体,ITON(或氧化氮化铟锡)。这种材料的性质和特性取决于其结构中所含的氮浓度。与ITO相比,带隙和电阻率等特性有所不同。ITON薄膜也具有较高的光响应。本文采用蒸发和PECVD法制备了氧化氮化铟锡薄膜,并对薄膜的电学参数进行了表征。在不同的温度下(140 ^{\circ}\ mathm {C}, 200 ^{\circ}\ mathm {C}, 260 ^{\circ}\ mathm {C}$和320 ^{\circ}\ mathm {C})$)$,通过等离子体退火将氮掺入到薄膜中,可以进一步改善ITON薄膜的光学和电学性能,从而使ITON薄膜成为理想的透明和导电材料。衬底为硅(75 mm, p型,1-10 ω .cm)和厚度为0.5 mm的光学3英寸玻璃晶圆。对薄膜进行光谱响应、电流×电压IxV和霍尔效应分析。本研究的主要目的是发展光电器件。电流-电压曲线显示了光的响应。通过光谱响应测量,可以验证基于ITON的器件在近红外区域具有更高的量子效率。总之,理想的情况是将这些材料应用于红外范围内的传感器。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrical characterization of indium tin oxynitride thin films for infrared sensor application
transparent conductive oxides (TCOs) are one class of materials with wide band gap ($\sim3.1$ eV). These materials have good transparency and conductivity. Indium Tin Oxide (ITO) is a degenerate semiconductor material with high band gap, transparent in the visible range of the solar spectrum and belonging to TCO class. When nitrogen is added to the ITO thin film, it is formed a new semiconductor, ITON (or indium tin oxynitride). The properties and characteristics of this material depend on the nitrogen concentration that is incorporated in its structure. Characteristics such as band gap and resistivity differ if compared to ITO. ITON thin film also has a higher light response. In this work, Indium Tin Oxynitride films were fabricated by evaporation and PECVD techniques and electrical parameters were characterized. Incorporation of nitrogen into the film by plasma annealing with different temperatures $(140 ^{\circ}\mathrm{C}, 200 ^{\circ}\mathrm{C}, 260 ^{\circ}\mathrm{C}$ and $320 ^{\circ}\mathrm{C})$ could improve further the optical and electrical properties of the ITON films and thus making ITON film an ideal transparent and conducting material for opto-electronic applications. Substrates were silicon (75 mm, p-type, 1-10 ohm.cm) and optical three-inch glass wafers with 0.5 mm thickness. The thin films were analyzed with spectral response, IxV (current x voltage) and Hall effect analyses. The main objective of this study is the development of optoelectronic devices. The current versus voltage curve show the response of light. With the spectral response measures it is possible to verify that ITON based devices have higher quantum efficiency for the near infrared region. In conclusion, the ideal would be the application of these materials in sensors that operate in the infrared range.
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