橡胶籽油生物柴油生产工艺优化及动力学研究

W. Aisabor, Y. Lukman, A. Otaru, A. E. Anakhu, S. Otoikhian
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引用次数: 0

摘要

由于人们对环境友好的渴望越来越强烈,人们对生物燃料产生了浓厚的兴趣,这导致了生物燃料的进一步研究和研究。寻找合适的植物油,可以像化石燃料一样工作,是生态友好的。因此,本研究探讨了从不可食用的巴西橡胶树油中生产生物柴油的方法。该工艺采用两步酸碱酯交换催化。研究了反应温度、反应时间等参数。在NaOH质量分数为1.0 wt %,甲醇:油摩尔比为6:1,反应时间为75 min的条件下,生物柴油的收率为50.2%。甘油三酯转化为甲酯遵循伪一级机理。测定了反应速率常数和活化能。测定了巴西螺和生物柴油的理化特性,并与标准值进行了比较。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimisation and Kinetics of Rubber Seed Oil Biodiesel Production
Due to the increasing yearn to go environment friendly, keen interest has been placed on biofuels, this leads to further studies and research in biofuels. A search for suitable vegetable/plant oil that can work just as fossil fuels and be ecofriendly was made. Hence, the study of this work investigates the production of biodiesel from non-edible Hevea brasiliensis oil. The process was catalysed by two-step acid base transesterification. Reaction parameters, such as reaction temperature and time were studied. The yield conversion of biodiesel was found to be 50.2% under the optimum conditions of 1.0 wt % NaOH and 6:1 methanol: oil molar ratio at 60°C for a reaction time of 75 min. The kinetic study was carried out at various temperatures. The conversion of triglycerides into methyl esters obeys the pseudo first-order mechanism. The reaction-rate constants and activation energies were determined. The physical and chemical characteristics of H. brasiliensis and biodiesel were determined and compared with standard value.
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