化学反应器设计中的输运现象

L. Belfiore
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引用次数: 19

摘要

前言。第一部分:化学反应器设计的基本问题。塞流管式反应器和连续搅拌槽式反应器中的多重化学反应。连续搅拌槽式反应器串联结构的启动特性。从一氧化碳和氢气可逆气相生成甲醇的绝热塞流管式反应器。具有强放热化学反应的非等温液相管式反应器的耦合传热传质。连续搅拌槽式反应器的多稳态。间歇式反应器中耦合传热传质与化学反应。反应速率数据分析的总压力法。第二部分:传输现象:基本原理和应用。变化方程在流体动力学中的应用。传质方程的推导。传质方程的量纲分析。固体球体、气泡和其他水下物体周围的层流边界层传质。传质边界层内流体动力变化方程的量纲分析。球形气液界面上的扩散和化学反应。第三部分:动力学和基本表面科学。非均相表面催化化学反应的动力学机理和速率表达式。第四部分:等温催化球团中的传质和化学反应。等温催化球团中的扩散和非均相化学反应。等温催化球团中扩散和零级化学反应的完全解析解。等温催化球团中扩散和一级化学反应的完全解析解。等温催化球团中扩散和n级化学反应的数值解。等温催化球团中扩散和Hougen-Watson化学动力学的数值解。等温催化球团的内部传质限制。催化球团内部孔内扩散系数和Damkohler数。第五部分:等温化学反应器设计。非均相填充催化反应器的等温设计。流道内壁涂覆金属催化剂的非均相催化反应器。设计多组份等温气液CSTR用于苯氯化制一氯苯。第六部分:热力学和非等温反应堆设计。多组分混合物的经典不可逆热力学。二元和多组分混合物中热能分子通量的非平衡热力学形式。多孔催化剂中多组分混合物的热能平衡及传热传质耦合的非等温效应因子。理想气体统计热力学。单相均质混合物的热力学稳定性准则。考虑外部输运限制的填料式催化管式反应器中的耦合传热和传质。参考文献。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Transport Phenomena for Chemical Reactor Design
Preface.PART I: ELEMENTARY TOPICS IN CHEMICAL REACTOR DESIGN.Multiple Chemical Reactions in Plug Flow Tubular Reactors and Continuous Stirred Tank Reactors.Start Up Behaviour of a Series Configuration of Continuous Stirred Tank Reactors.Adiabatic Plug-Flow Tubular Reactor That Produces Methanol Reversibly in the Gas Phase from Carbon Monoxide and Hydrogen.Coupled Heat and Mass Transfer in Nonisothermal Liquid-Phase Tubular Reactors with Strongly Exothermic Chemical Reactions.Multiple Stationary States in Continuous Stirred Tank Reactors.Coupled Heat and Mass Transfer with Chemical Reaction in Batch Reactors.Total Pressure Method of Reaction-Rate Data Analysis.PART II: TRANSPORT PHENOMENA: FUNDAMENTALS AND APPLICATIONS.Applications of the Equations of Change in Fluid Dynamics.Derivation of the Mass Transfer Equation.Dimensional Analysis of the Mass Transfer Equation.Laminar Boundary Layer Mass Transfer around Solid Spheres, Gas Bubbles, and Other Submerged Objects.Dimensional Analysis of the Equations of Change for Fluid Dynamic s Within the Mass Transfer Boundary Layer.Diffusion and Chemical Reaction Across Spherical Gas-Liquid Interfaces.PART III: KINETICS AND ELEMENTARY SURFACE SCIENCE.Kinetic Mechanisms and Rate Expressions for Heterogeneous Surface-Catalyzed Chemical Reactions.PART IV: MASS TRANSFER AND CHEMICAL REACTION IN ISOTHERMAL CATALYTIC PELLETS.Diffusion and Heterogeneous Chemical Reaction in Isothermal Catalytic Pellets.Complete Analytical Solutions for Diffusion and Zeroth-Order Chemical Reactions in Isothermal Catalytic Pellets.Complete Analytical Solutions for Diffusion and First-Order Chemical Reactions in Isothermal Catalytic Pellets.Numerical Solutions for Diffusion and nth-Order Chemical Reactions in Isothermal Catalytic Pellets.Numerical Solutions for Diffusion and Hougen-Watson Chemical Kinetics in Isothermal Catalytic Pellets.Internal Mass Transfer Limitations in Isothermal Catalytic Pellets.Diffusion Coefficients and Damkohler Numbers Within the Internal Pores of Catalytic Pellets.PART V: ISOTHERMAL CHEMICAL REACTOR DESIGN.Isothermal Design of Heterogeneous Packed Catalytic Reactors.Heterogeneous Catalytic Reactors with Metal Catalyst Coated on the Inner Walls of the Flow Channels.Designing a Multicomponent Isothermal Gas-Liquid CSTR for the Chlorination of Benzene to Produce Monochlorobenzene.PART VI: THERMODYNAMICS AND NONISOTHERMAL REACTOR DESIGN.Classical Irreversible Therodynamics of Multicomponent Mixtures.Molecular Flux of Thermal Energy in Binary and Multicomponent Mixtures Via the Formalism of Nonequilibrium Thermodynamics.Thermal Energy Balance in Multicomponent Mixtures and Nonisothermal Effectiveness Factors Via Coupled Heat and Mass Transfer in Porous Catalysts.Statistical Thermodynamics of Ideal Gases.Thermodynamic Stability Criteria for Single-Phase Homogeneous Mixtures.Coupled Heat and Mass Transfer in Packed Catalytic Tubular Reactors That Account for External Transport Limitations.References.Index.
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